Abstract：The principles,characteristics and application range of various radiometric and chemical analysis methods for uranium are reviewed.The methods of radiometric analysis mainly include α spectrum,γ-ray spectrometry,ueutron activation method and fission track method.The chemical analysis methods mainly include volumetry/titration,spectrophotometry/colorimetry,electrochemical method,fluorescence photometry,laser-induced fluorescence method/ultraviolet pulse fluorescence method,X-ray fluorescence spectrometry(XRF),inductively coupled plasma atomic emission spectrometry(ICP-AES),thermal ionization mass spectrometry(TIMS),inductively coupled plasma mass spectrometry(ICP-MS),etc.The advantages and disadvantages of different methods are compared according to the actual measurement needs.Moreover,the development prospect of analysis methods for uranium is forecasted.
梁志荣,陈琦,刘学军.α能谱法测定土壤样品中的235U、238U[J].核化学与放射化学,2007,29(1):57-59.LIANG Zhirong,CHEN Qi,LIU Xuejun.Determination of 235U and 238U in soil by alpha spectrometry[J].Journal of Nuclear and Radiochemistry,2007,29(1):57-59.
[2]
Hassan J,Mozaffari S,Abbas A.Determination of uranium in aqueous samples by thin-film solid phase extraction and alpha spectrometry[J].Anal.Chem.Ind.J.,2016,16(14):106.
[3]
何乐龙,辛文彩,张剑,等.海洋沉积物光释光测年中铀、钍、钾的γ能谱法分析[J].海洋地质前沿,2018,34(12):68-76.HE Lelong,XIN Wencai,ZHANG Jian,et al.γ-Spectrometric determination of U,Th and K for OSL dating of marine sediments[J].Marine Geology Frontiers,2018,34(12):68-76.
[4]
陈敏,张成江,倪师军.仪器中子活化法研究核设施周围土壤中的铀、钍、钾[J].核化学与放射化学,2010,32(5):315-320.CHEN Min,ZHANG Chengjiang,NI Shijun.Study on uranium,thorium and potassium in soil around a nuclear installation by using INAA[J].Journal of Nuclear and Radiochemistry,2010,32(5):315-320.
[5]
张峰.用裂变径迹法研究云贵高原洱海和南明河中铀含量[J].水科学进展,1996,7(2):163-166.ZHANG Feng.A study of the uranium contents in Er-Sea and Nanming River on Yunnan-Guizhou Plateau using fission track method[J].Advance in Water Science,1996,7(2):163-166.
[6]
刘立坤,郭冬发,黄秋红.岩石矿物中铀钍的分析方法进展-非破坏分析法[J].中国无机分析化学,2012,2(4):10-14.LIU Likun,GUO Dongfa,HUANG Qiuhong.Review on the analytical methods for determination of uranium and thorium in rocks and minerals-non-destructive analysis[J].Chinese Journal of Inorganic Analytical Chemistry,2012,2(4):10-14.
[7]
穆佩娟,程文康.滴定法测定矿物中铀[J].化学分析计量,2018,27(5):59-63.MU Peijuan,CHENG Wenkang.Determination of uranium in minerals by titration[J].Chemical Analysis and Meterage,2018,27(5):59-63.
[8]
杜浪,李玉香,马雪,等.偶氮胂Ⅲ分光光度法测定微量铀[J].冶金分析,2015,35(1):68-71.DU Lang,LI Yuxiang,MA Xue,et al.Determination of micro uranium by arsenazo Ⅲ spectrophotometry[J].Metallurgical Analysis,2015,35(1):68-71.
杨亚新,肖赛金,刘庆成,等.空气中痕量铀的现场光度法测定[J].光谱学与光谱分析,2012,32(7):1939-1942.YANG Yaxin,XIAO Saijin,LIU Qingcheng,et al.Detection of trace uranium in air with field spectrometry[J].Spectroscopy and Spectral Analysis,2012,32(7):1939-1942.
[11]
王岚,黎春,张继龙,等.基于Davies-Gray电位滴定法精密测定25~50 mg铀含量[J].核化学与放射化学,2019,41(6):573-577.WANG Lan,LI Chun,ZHANG Jilong,et al.Precision measuring 25-50 mg uranium concentration by davies-gray potentiometric titration method[J].Journal of Nuclear and Radiochemistry,2019,41(6):573-577.
[12]
黎金标,谢振键,马立奎.微波消解全自动电位滴定法快速测定岩石中的铀[J].铀矿地质,2018,34(6):366-370.LI Jinbiao,XIE Zhenjian,MA Likui.Rapid determination of uranium in rock by automatic potentiometric titration with microwave digestion[J].Uranium Geology,2018,34(6):366-370.
[13]
丁海云,陈强,周丽华.用汞膜修饰玻碳电极检测低浓度铀(Ⅵ)[J].湿法冶金,2016,35(2):162-166.DING Haiyun,CHEN Qiang,ZHOU Lihua.Determination of trace uranium(Ⅵ) at the mercury film modified glassy carbon electrode[J].Hydrometallurgy of China,2016,35(2):162-166.
[14]
李弘杨,韩世同,唐云飞.基于脱氧核酶的水中铀酰离子荧光检测方法研究[J].环境科学学报,2017,37(10):3635-3641.LI Hongyang,HAN Shitong,TANG Yunfei.DNAzyme-based fluorescent detection of uranyl ion in water samples[J].Acta Scientiae Circumstantiae,2017,37(10):3635-3641.
[15]
周斌,胡淦彬,杨慧仙,等.基于DNAzyme与铀特异性反应的共振光散射法检测铀[J].分析试验室,2016,35(1):12-16.ZHOU Bin,HU Ganbin,YANG Huixian,et al.Determination of uranyl based on uranyl specific DNAzyme by a resonance light scattering technique[J].Chinese Journal of Analysis Laboratory,2016,35(1):12-16.
[16]
姜交来,王芸,肖吉群.基于DNA酶的铀酰离子传感方法[J].核化学与放射化学,2018,40(2):89-99.JIANG Jiaolai,WANG Yun,XIAO Jiqun,et al.Uranyl ion sensing methods based on DNAzyme[J].Journal of Nuclear and Radiochemistry,2018,40(2):89-99.
[17]
胡家宁,林娜,高博,等.有机荧光探针在铀酰离子检测方面的研究进展[J].核化学与放射化学,2018,40(6):337-348.HU Jianing,LIN Na,GAO Bo,et al.Progress of organic fluorescent probes in uranyl ion detection[J].Journal of Nuclear and Radiochemistry,2018,40(6):337-348.
[18]
孙秉怡,全葳,卢瑛.微波消解-激光荧光法测定土壤样品中微量铀[J].核化学与放射化学,2017,39(4):268-272.SUN Bingyi,QUAN Wei,LU Ying.Determination of trace uranium in soil samples by microwave digestion-laser fluorescence method[J].Journal of Nuclear and Radiochemistry,2017,39(4):268-272.
[19]
郑新艳,周小娇,鲁霞.紫外脉冲荧光法测定微量铀的研究[J].原子核物理评论,2016,33(1):57-60.ZHENG Xinyan,ZHOU Xiaojiao,LU Xia,et al.Determination of trace uranium by the method of pulse ultraviolet fluorescence[J].Nuclear Physics Review,2016,33(1):57-60.
[20]
经辉.X射线荧光光谱法同时测定矿石中铀和钍[J].中国无机分析化学,2015,5(3):34-40.JING Hui.Simultaneous determination of uranium and thorium in ores by X-ray fluorescence spectrometry[J].Chinese Journal of Inorganic Analytical Chemistry,2015,5(3):34-40.
[21]
程锋,葛良全,赖万昌,等.新一代便携式X射线荧光仪及其在铀分析中的初步应用[J].铀矿地质,2008,24(6):375-379.CHENG Feng,GE Liangquan,LAI Wanchang,et al.The preliminary application of a new portable uranium X-ray fluorescence analyzer[J].Uranium Geology,2008,24(6):375-379.
[22]
王成玲.电感耦合等离子体发射光谱法测定地质样品中的铀含量[J].化工时刊,2018,32(6):20-22.WANG Chengling.Determination of uranium content in geological samples by inductively coupled plasma atomic emission spectrometry[J].Chemical Industry Times,2018,32(6):20-22.
[23]
刘欣,臧旭芳,时燕华.ICP-OES测量岩矿中铀的干扰分析[J].四川有色金属,2019(3):41-43.LIU Xin,ZANG Xufang,SHI Yanhua.Analysis on uranium element measurement interference by inductively coupled plasma optical emission spectroscopy (ICP-OES) [J].Sichuan Nonferrous Metals,2019(3):41-43.
[24]
李金英,郭冬发,吉燕琴,等.电感耦合等离子体质谱、热电离质谱和二次离子质谱技术在核工业中的新进展[J].质谱学报,2010,31(5):257-263.LI Jinying,GUO Dongfa,JI Yanqin,et al.Recent progress of nuclear technological application for inductively coupled plasma mass spectrometry(ICP-MS),thermal ionization mass spectrometry(TIMS) and secondary ion mass spectrometry(SIMS) [J].Journal of Chinese Mass Spectrometry Society,2010,31(5):257-263.
[25]
郝樊华,刘雪梅,胡思得,等.热表面电离质谱法测定贫化铀样品痕量铀同位素比值及含量[J].岩矿测试,2010,29(4):373-376.HAO Fanhua,LIU Xuemei,HU Side,et al.Determination of isotope ratios and concentration of trace uranium in depleted uranium samples by thermal ionization mass spectrometry[J].Rock and Mineral Analysis,2010,29(4):373-376.
[26]
何学贤,刘敦一,杨淳,等.热电离质谱(TIMS)铀系定年技术的误差来源分析[J].地质论评,2002,48(增刊):161-164.HE Xuexian,LIU Dunyi,YANG Chun,et al.Analysis of the error sources in the thermal ionization mass spectrometry uranium series dating technique[J].Geological Review,2002,48(sup.):161-164.
[27]
郭国龙,王春叶,丁红芳,等.微波消解-电感耦合等离子体质谱法测定粉煤灰中铀[J].冶金分析,2019,39(6):20-23.GUO Guolong,WANG Chunye,DING Hongfang,et al.Determination of uranium in coal fly ash by inductively coupled plasma mass spectrometry with microwave digestion[J].Metallurgical Analysis,2019,39(6):20-23.
[28]
鲁业明,孙鹏,梁帮宏.人体尿液中痕量铀的高分辨电感耦合等离子体质谱测定方法研究[J].中国辐射卫生,2017,26(2):224-226.LU Yeming,SUN Peng,LIANG Banghong.Determination of trace uranium in human urine by high resolution-inductive coupled plasma mass spectrometry[J].Chinese Journal of Radiological Health,2017,26(2):224-226.
[29]
刘立坤,郭冬发,黄秋红.岩石矿物中铀钍的分析方法进展-湿法化学法[J].中国无机分析化学,2012,2(2):6-9.LIU Likun,GUO Dongfa,HUANG Qiuhong.Progress in analytical methods for determination of uranium and thorium in rocks and minerals-wet chemical analysis[J].Chinese Journal of Inorganic Analytical Chemistry,2012,2(2):6-9.
[30]
黄微,高鹏,宫增艳.电感耦合等离子体质谱法与液体激光荧光法分析水中铀的比较[J].中国辐射卫生,2019,28(5):569-571.HUANG Wei,GAO Peng,GONG Zengyan.Comparison of methods for analysis of uranium in water by inductively coupled plasma mass spectrometry and liquid laser fluorescence[J].Chinese Journal of Radiological Health,2019,28(5):569-571.
[31]
粟永阳,李志明,徐江,等.气载、液载颗粒物直接进样ICP-MS技术及其在核工业中的应用[J].质谱学报,2019,40(5):447-459.SU Yongyang,LI Zhiming,XU Jiang,et al.Direct introduction of airborne and suspension particles in to ICP-MS for on-line elemental or isotopic analysis and its application in nuclear field[J].Journal of Chinese Mass Spectrometry Society,2019,40(5):447-459.
