X射线荧光光谱在锰系合金分析中的应用文献评介

doi:10.13228/j.boyuan.issn1000-7571.011210

摘要
图/表
参考文献
相关文章 (15)

全文: PDF (926 KB) HTML (1 KB)
输出: BibTeX | EndNote (RIS)

摘要 X射线荧光光谱(XRF)被广泛应用于锰系合金的分析,具有检测速度快、分析精度高、重现性好的特点。文章收集了近20年来锰系合金(硅锰合金、锰铁)中硅、锰、磷等元素的X射线荧光光谱测定方法文献36篇,其中压片制样23篇,熔融制样13篇。重点介绍了压片制样和熔融制样的具体应用情况,并对这两种方法的优缺点作了简要的评述。

	服务

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	李新家
	乔蓉

关键词 ： X射线荧光光谱(XRF), 硅锰合金, 锰铁, 应用研究

Abstract：X-ray fluorescence spectroscopy (XRF) has been widely used in the analysis of manganese series alloys. It has the characteristics of fast detection speed, high analytical precision and good reproducibility. Total 36 articles concerning the determination methods of silicon, manganese and phosphorus in manganese series alloys (silicomanganese and ferromanganese) by XRF were summarized. Among them, 23 articles were about pressing sample preparation and 13 articles were about melting sample preparation. The application of these two methods was introduced, and their advantages and disadvantages were also briefly reviewed.

Key words： X-ray fluorescence spectrometry (XRF) silicomanganese alloy ferromanganese applicationresearch

收稿日期: 2020-06-16

ZTFLH:

O657.34

作者简介: 李新家(1964—),男,高级工程师,硕士,长期从事冶金材料分析技术研究;E-mail: leesinko@163.com

引用本文:

李新家, 乔蓉. X射线荧光光谱在锰系合金分析中的应用文献评介[J]. 冶金分析, 2021, 41(6): 16-26. LI Xinjia, QIAO Rong. Review on the application of X-ray fluorescence spectrometry in analysis of manganese alloy. , 2021, 41(6): 16-26.

链接本文:

http://yjfx.chinamet.cn/CN/10.13228/j.boyuan.issn1000-7571.011210 或 http://yjfx.chinamet.cn/CN/Y2021/V41/I6/16

[1] 伯廷(E.P.Bertin).X射线光谱分析导论[M].高新华,译.北京:地质出版社,1981.
[2] 谢忠信,赵宗铃,张玉斌,等.X射线光谱分析[M].北京:科学出版社,1982.
[3] 特希昂,克莱特. X 射线荧光定量分析原理[M].高新华等,译.北京:冶金部钢铁研究总院,1984.
[4] 吉昂,陶光仪,卓尚军,等.X 射线荧光光谱分析[M].北京:科学出版社,2003.
[5] 梁钰.X射线荧光光谱分析基础[M].北京:科学出版社,2007.
[6] 高新华,宋武元,邓赛文,等.实用X射线光谱分析[M].北京:化学工业出版社,2017.
[7] 聂富强,李景滨.X射线荧光光谱分析铁合金样品的制备方法进展[J].化学工程与装备(Chemical Engineering & Equipment),2010(11):132-134.
[8] 游华,刘梅山,徐文荣.X射线荧光光谱法测定硅锰合金[J].福建分析测试,2001,10(1):1363-1365.
YOU Hua,LIU Meishan,XU Wenrong.XRF spectrometry of silicomanganese ferroalloy using pressed disc sampling of the sample powder[J].Fujian Analysis & Testing,2001,10(1):1363-1365.
[9] 丁明,李小杰,沈克,等.X射线荧光光谱法测定硅铁和硅锰合金中常规元素[C]//2007年直读光谱仪及X 荧光光谱仪用户技术交流会论文汇编.北戴河:全国轧钢信息网,2007:102-105.
[10] 薛萍,刘春红,王雅. X射线荧光直接压片法测定硅锰合金中的硅、锰、磷元素[C]//帕纳科中国第十届X射线分析仪器用户技术交流会论文集.大连:帕纳科中国用户协会,2008:321-328.
[11] 周春丽,张妍萍,田国靖,等.X射线荧光光谱压片法测定硅锰铁合金中Mn、Si、P等元素[J].军工计量,2011(增):19-20,50.
ZHOU Chunli,ZHANG Yanping,TIAN Guojing,et al.Determination of Mn,Si,P in ferro-silico-manganese alloy by X-ray fluorescence spectrometry[J].Military Measurement,2011(suppl.):19-20,50.
[12] 沈奇,刘久平,李刚,等.X荧光光谱法快速测定硅锰合金中硅、锰、磷[J].理化检验(化学分册),2012,48(2):256-258.
SHEN Qi,LIU Jiuping,LI Gang,et al.Determination of silicon,manganese and phosphorus in silicon-manganese alloys by X fluorescence spectrometry[J].Physical Testing and Chemical Analysis(Part B:Chemical Analysis),2012,48(2):256-258.
[13] 王剑云.X-荧光光谱法分析硅锰中的化学元素[J].浙江冶金,2013(3):44-45.
WANG Jianyun.Analysis of chemical elements in silicon manganese by X-fluorescence spectrometry[J]. Zhejiang Metallurgy,2013(3):44-45.
[14] 罗建武,易婷,廖子云.X荧光光谱法测定锰铁和硅锰合金中常规元素[J].科技风,2017,18:239-240.
LUO Jianwu,YI Ting,LIAO Ziyun.Determination of conventional elements in ferromanganese and ferromanganese alloys by X fluorescence spectrometry[J].Technology Wind,2017,18:239-240.
[15] 孙闯.X荧光光谱压片法测定硅锰铁合金中的Mn、Si、P元素[J].南钢科技与管理,2017(3):46-51,58.
SUN Chuang.Measuring the content of Mn,Si,P in ferro-silico-manganese alloy by X fluorescence spectrum pellet method[J].NISCO Technology and Management,2017(3):46-51,58.
[16] 于桂萍.X射线荧光光谱分析方法测定锰硅合金中钛的质量分数[J].铁合金,2008(4):42-44.
YU Guiping.Determining titanium content in ferromanganese-silicon by X-ray fluorescence spectrum analysis method[J].Ferro-alloys,2008(4):42-44.
[17] 刘光蓉.压片制样-X射线荧光光谱法测定普硅锰硅合金中的Ti[J].铁合金,2015(12):38-40.
LIU Guangrong.Determination of Ti in standard ferromanganese-silicon by X ray fluorescence spectrometry with tablet-compression sampling[J].Ferro-alloys,2015(12):38-40.
[18] 舒钧,陈君,罗喜清.铁合金的X-射线荧光光谱分析[J].江苏冶金,2001(4):50-51.
SHU Jun,CHEN Jun,LUO Xiqing.X-ray fluorescence spectral analysis of ferroalloys[J].Jiangsu Metallurgy, 2001(4):50-51.
[19] 伊志宏,于想琼.硅锰合金的X-射线荧光分析[J].华东地质学院学报,2001,24(2):157-159.
YI Zhihong,YU Xiangqiong.Analysis of silico manganese alloy by X-ray[J].Journal of East China Geological Institute,2001,24(2):157-159.
[20] 胡正阳,邢华宝,华静,等.X射线荧光光谱法测定复合碳硅锰中的硅、锰、磷[J].冶金分析,2003,23(3):51-52.
HU Zhengyang,XING Huabao,HUA Jing,et al.Determination of Si,Mn and P in the carbon silico manganese compound materials by X ray fluorescence spectrometry[J].Metallurgical Analysis,2003,23(3):51-52.
[21] 彭文明,边立槐,钟静.X射线荧光光谱法对硅锰合金中多元素的同时分析[J].天津冶金,2005(4):39-41.
PENG Wenming,BIAN Lihuai,ZHONG Jing.Simultaneous analysis of multi-element in Si-Mn alloys with X-rays fluorimetry[J].Tianjin Metallurgy,2005(4):39-41.
[22] 王小武,梁艳容.X-荧光光谱法测定硅锰合金中主元素Mn含量的研究[J].冶金丛刊,2006(5):34-36.
WANG Xiaowu,LIANG Yanrong.Research on determining the content of Mn in Mn-Si alloy by X-ray fluorescence spectometry[J].Metallurgical Collections,2006(5):34-36.
[23] 马秀艳,武映梅,王震,等.X射线荧光光谱法分析锰铁[J].南方金属,2008,160:49-51.
MA Xiuyan,WU Yingmei,WANG Zhen,et al.XRF analysis of ferromanganese[J].Southern Metals, 2008,160:49-51.
[24] 耿艳霞,许鸿英,郭利军.X-射线荧光法分析硅锰合金影响因素的探讨[C]//第十四届冶金及材料分析测试学术报告会论文集.北京:中国金属学会,2008:230-232.
[25] 苗斌,徐鸿英,冯建航.用X射线荧光分析仪分析硅锰合金中的硅锰[J].河北冶金,2009(3):51-52.
MIAO Bin,XU Hongying,FENG Jianhang.Analysis of silicon and manganese in silicon-manganese alloy with X-ray fluorimeter[J].Hebei Metallurgy,2009(3):51-52.
[26] 孙春丽,郑建道,万冬林,等.锰硅X荧光光谱分析的研究[J].甘肃冶金,2010,32(5):129-130,132.
SUN Chunli,ZHENG Jiandao,WAN Donglin,et al.Study on the analysis of manganese-silicon by X fluorescence spectroscopy[J].Gansu Metallurgy,2010,32(5):129-130,132.
[27] 梁鹏山.X射线荧光光谱法测定锰铁中的锰、磷、硅[J].科技创新导报,2011(14):12.
LIANG Pengshan.Determination of Mn,Si and P in ferromanganese by X-ray fluorescence spectrometry[J].Science and Technology Innovation Herald,2011(14):12.
[28] 赵宁,王良根.硅锰合金X-射线荧光分析法[J].南钢科技与管理,2015(4):51-54.
ZHAO Ning,WANG Lianggen.Analysis on silicomanganese alloy by X-ray fluorescence analysis method[J].NISCO Technology and Management,2015(4):51-54.
[29] 姚峰,何勐喆. X射线荧光光谱法测定锰铁中的主要元素[J].科研(Study of Science),2016(12):299-300.
[30] 高云.X射线荧光光谱法快速测定硅锰、硅铁合金中硅锰磷硫含量的测定[J].世界有色金属,2019(7):255-256.
GAO Yun.Rapid detemination of Si-Mn phphosphorus and sulfur content in Si-Mn and Si-Fe alloys by X-ray fluorescence spectrometry[J].World Nonferrous Metals,2019(7):255-256.
[31] (加)克拉斯,(加)布兰切特.硼酸盐熔融的物理和化学[M].卓尚军,译.上海:华东理工大学出版社,2006.
[32] 李国会,李小莉.X射线荧光光谱分析熔融法制样的系统研究[J].冶金分析,2015,35(7):1-9.
LI Guohui,LI Xiaoli.Systematic study on the fusion sample preparation in X-ray fluorescence spectrometric analysis[J].Metallurgical Analysis,2015,35(7):1-9.
[33] 张璐,龚宜勇.熔融法在X荧光分析硅锰合金中的应用[J].天津冶金,2000(5):25-27.
ZHANG Lu,GONG Yiyong.Application of the melting method to Si-Mn alloy’s XRF[J].Tianjin Metallurgy,2000(5):25-27.
[34] 王彬果,赵靖,徐静,等.熔融制样X射线荧光光谱法测定锰铁合金中硅、锰和磷含量[J].光散射学报,2011,23(2):177-180.
WANG Binguo,ZHAO Jing,XU Jing,et al.Determination of Si,Mn and P in ferromanganese by X-ray fluorescence by fusion method[J].The Journal of light scattering,2011,23(2):177-180.
[35] 李宗超,曹兴旺,马文广,等. X射线荧光光谱法分析硅锰合金中的硅、锰、磷[J].检验检疫学刊,2015,25(2):47-49.
LI Zongchao,CAO Xingwang,MA Wenguang,et al.Analysis of silicon,manganese,phosphorus in silicon manganese alloy by X-ray fluorescence spectrometry[J].Journal of Inspection and Quarantine,2015,25(2): 47-49.
[36] 邢文青,吴超超,王岩,等. X射线荧光熔融法测定锰系合金中硅、锰和磷含量[J].南方金属,2016(6):8-10.
XING Wenqing,WU Chaochao,WANG Yan,et al.Determination of contents of Mn,Si and P in manganese ferroalloys by X-ray fluorescence spectrometer[J].Southern Metals,2016(6):8-10.
[37] 李建民.熔融制样-X射线荧光光谱法测定硅锰合金中的硅、锰和磷[J].理化检验(化学分册)(Physical Testing and Chemical Analysis (Part B:Chemical Analysis)),2016,52 (4):484-486.
[38] 吴超超,陈自斌,邢文青,等. 熔融制样-X射线荧光光谱法测定锰铁、硅锰合金中锰硅磷[J].冶金分析, 2018,38(3):14-21.
WU Chaochao,CHEN Zibin,XING Wenqing,et al.Determination of manganese,silicon,phosphorus in ferromanganese and siliconmanganese alloy by X-ray fluorescence spectrometry with fusion sample preparation[J].Metallurgical Analysis,2018,38(3):14-21.
[39] 刘伟,曹吉祥,郭云涛,等.熔融制样-X射线荧光光谱法测定硅锰合金中硅锰磷[J].冶金分析,2015,35(8):51-54.
LIU Wei,CAO Jixiang,GUO Yuntao,et al.Determination of silicon,manganese,phosphorus in silicon manganese alloy by X-ray fluorescence spectrometry with fusion sample preparation[J].Metallurgical Analysis,2015,35(8):51-54.
[40] 徐建平.四硼酸锂坩埚内预氧化熔融制样-X射线荧光光谱法测定锰铁及锰硅合金中的硅、锰、磷[J].理化检验(化学分册)(Physical Testing and Chemical Analysis (Part B:Chemical Analysis)),2016,52(11):1344-1346.
[41] 李京.熔融制样-X射线荧光光谱法测定锰铁中锰硅磷[J].冶金分析,2011,31(6):51-53.
LI Jing.Determination of manganese,silicon and phosphorus in ferromanganese by X-xay fluorescence spectrometry with fusion sample preparation[J].Metallurgical Analysis,2011,31(6):51-53.
[42] 张秀芳,陆晓明.熔融制样-X射线荧光光谱法测定锰铁中硅、锰、磷、铬、镍和铜[J].理化检验(化学分册),2015,51(8):1110-1112.
ZHANG Xiufang,LU Xiaoming.XRFS determination of silicon,manganese,phosphorus,chromium,nickel and copper in ferromanganese with sample preparation by fusion[J]. Physical Testing and Chemical Analysis(Part B:Chemical Analysis),2015,51(8):1110-1112.
[43] 李小青.熔融制样-X射线荧光光谱法测定锰铁和金属锰中锰硅磷[J].冶金分析,2018,38(6):39-42.
LI Xiaoqing.Determination of manganese,silicon,phosphorus in ferromanganese and manganese metal by X-ray fluorescence spectrometry with fusion sample preparation[J].Metallurgical Analysis,2018,38(6):39-42.
[44] 鲍希波,赵亮,李才红,等.熔融制样-X射线荧光光谱法测定硅锰合金和锰铁合金中硅锰磷铁[J].冶金分析,2019,39(2):51-55.
BAO Xibo,ZHAO Liang,LI Caihong,et al.Determination of silicon,manganese,phosphorus and iron in siliconmanganese and ferromanganese alloy by X-ray fluorescence spectrometry with fusion sample preparation[J].Metallurgical Analysis,2019,39(2):51-55.
[45] 陆晓明,金德龙.离心浇铸制样-X射线荧光光谱法测定锰铁中锰硅磷[J].冶金分析,2008,28(9):34-37.
LU Xiaoming,JIN Delong.Determination of manganese,silicon,phosphorus in ferromanganese by X-ray fluorescence spectrometry with centrifugal casting preparation of sample[J].Metallurgical Analysis,2008,28(9):34-37.
[46] 李可及.X射线荧光光谱熔融制样分析金属及合金的酸碱预氧化方法[J].冶金分析,2016,36(4):76-79.
LI Keji.Acid or alkali pre-oxidization method for fusion sample preparation in X-ray fluorescence spectrometric determination of metals and alloys[J].Metallurgical Analysis,2016,36(4):76-79.
[47] 杨新能,李小青,杨大军.X射线荧光光谱法测定含还原剂的炼钢辅料中化学成分[J].冶金分析,2014,34(2):40-43.
YANG Xinneng,LI Xiaoqing,YANG Dajun.Determination of chemical composition of steelmaking auxiliary materials containing reducing agents by X-ray fluorescence spectrometry[J].Metallurgical Analysis, 2014,34(2):40-43.
[48] 李仲轩,赵天宝.XRF测定硅铁的制样方法研究[J].光谱实验室,1998,15(2):83-86.
LI Zhongxuan,ZHAO Tianbao.A study on the sample preparation method in ferrosilicon XRF determination[J].Chinese Journal of Spectroscopy Laboratory,1998,15(2):83-86.
[49] 赵耀. XRF 法分析硫化物矿的试样制备[J].冶金分析,2001,21(5):67-68.
ZHAO Yao.Preparation of sample for the analysis of sulphide ores by XRF[J].Metallurgical Analysis,2001,21(5):67-68.
[50] 殷绍泉,邓赛文,王毅民,等. X射线荧光光谱在铜矿石分析中的应用文献评介[J].冶金分析,2019,39(7):43-52.
YIN Shaoquan,DENG Saiwen,WANG Yimin,et al.Review on the application of X-ray fluorescence spectrometry in copper ore analysis[J].Metallurgical Analysis,2019,39(7):43-52.
[51] 邓赛文,王毅民,孙晓飞,等. X射线荧光光谱技术在铁矿石分析中的应用文献评介[J].冶金分析,2019, 39(11):30-49.
DENG Saiwen,WANG Yimin,SUN Xiaofei,et al.Review on the application of X-ray fluorescence spectroscopy in the analysis of iron ores[J].Metallurgical Analysis,2019,39(11):30-49.