Abstract：At present, X-ray fluorescence spectrometry (XRF) has become one of the most important methods for the analysis of manganese ore. Total 29 papers about the analysis of manganese ore by XRF in China by 2020 were collected, wherein 25 of them adopted the fusion sample preparation method and 4 of them adopted the pressed powder pellet for sample preparation. The article introduced the literature overview and basic conditions of manganese ore analysis in China, including related monographs, review papers, certified reference materials and standard methods. The main points in 29 papers were introduced by the means of list, including instrument, sample preparation method, calibration and matrix correction, component determinated and determination precision. The typical and representative literatures were focused on according to the sample preparation method. It emphasized that although the fusion sample preparation could effectively solve the influence of sample size and mineral effect, the development of pressed powder pellet method still had unique advantages and social development needs. Finally, the selection of sample preparation method, the influence of sample size, and the future development trend of XRF in the analysis of manganese ore were discussed.
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