Application progress of high resolution inductively coupled plasma mass spectrometry in determination of trace element in geological samples
LI Tong1,2, SHEN Kangjun1, ZHU Yaguan1, MIN Hong*1, LI Chen1, LIU Shu*1
1. Technical Center for Industrial Product and Raw Material Inspection and Testing, Shanghai Customs, Shanghai 200135, China; 2. Chemical Engineering and Biotechnology, Key Laboratory of Science and Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
Abstract：High resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) is an element and isotope analysis technology using inductively coupled plasma as ion source and sector magnetic field mass spectrometry as detector. It has the advantages of high sensitivity, low limit of detection and simultaneous analysis of multiple elements. As the simplest and most effective technology to overcome the interference of mass spectrometry, HR-ICP-MS has been gradually applied in geology, environment, metallurgy, biology and other fields. The principle and technical characteristics of HR-ICP-MS are briefly introduced, and the pretreatment methods of geological samples commonly used in the laboratory are summarized. The advantages and disadvantages of these pretreatment methods are compared. The application progress of HR-ICP-MS is analysis of conventional elements, rare earth elements and rare and scattered elements in geological samples in recent 10 years was summarized. HR-ICP-MS could solve the mass spectrum interference of most isoelements, polyatoms and oxides. Internal standard method, matrix matching method, isotope dilution method and matrix separation technology could solve the matrix effect in HR-ICP-MS analysis. The combination of HR-ICP-MS with laser ablation and morphological separation was also worthy of attention in the future.
李彤, 沈康俊, 朱亚冠, 闵红, 李晨, 刘曙. 高分辨电感耦合等离子体质谱分析地质样品中痕量元素的应用进展[J]. 冶金分析, 2021, 41(4): 9-19.
LI Tong, SHEN Kangjun, ZHU Yaguan, MIN Hong, LI Chen, LIU Shu. Application progress of high resolution inductively coupled plasma mass spectrometry in determination of trace element in geological samples. , 2021, 41(4): 9-19.
白金峰,薄玮,张勤,等.高分辨电感耦合等离子体质谱法测定地球化学样品中的36种元素[J].岩矿测试,2012,31(5):814-819.BAI Jinfeng,BO Wei,ZHANG Qin,et al.Determination of 36 elements in geochemical samples by high resolution inductively coupled plasma-mass spectrometry[J].Rock and Mineral Analysis,2012,31(5):814-819.
[2]
Bolea-Fernandez E,Balcaen L,Resano M,et al.Overcoming spectral overlap via inductively coupled plasma-tandem mass spectrometry (ICP-MS/MS). A tutorial review [J].Journal of Analytical Atomic Spectrometry,2017,32(9):1660-1679.
[3]
Balcaen L,Bolea-Fernandez E,Resano M,et al.Inductively coupled plasma-tandem mass spectrometry (ICP-MS/MS): a powerful and universal tool for the interference-free determination of (ultra)trace elements-a tutorial review [J].Analytica Chimica Acta,2015,894:7-19.
[4]
Liu X B,Piao J H,Huang Z W,et al.Determination of 16 selected trace elements in children plasma from China economical developed rural areas using high resolution magnetic sector inductively coupled mass spectrometry [J].Journal of Analytical Methods in Chemistry,2014,2014:1-6.
[5]
Thompson R L,Bank T,Roth E,et al.Resolution of rare earth element interferences in fossil energy by-product samples using sector-field ICP-MS [J]. Fuel,2016,185:94-101.
[6]
聂玲清,纪红玲,陈英颖,等.基体未分离高分辨电感耦合等离子体质谱法测定钢中痕量元素[J].冶金分析,2007,27(2):18-23.NIE Lingqing,JI Hongling,CHEN Yingying,et al.Determination of trace elements in steel by high resolution inductively coupled plasma mass spectrometry without matrix separation[J].Metallurgical Analysis,2007,27(2):18-23.
[7]
胡净宇,王海舟.ICP-MS在冶金分析中的应用进展[J].冶金分析,2001,21(6):27-32.HU Jingyu,WANG Haizhou.Progress in application of ICP-MS in metallurgical analysis[J].Metallurgical Analysis,2001,21(6):27-32.
[8]
Herwig N,Stephan K,Panne U,et al.Multi-element screening in milk and feed by SF-ICP-MS[J].Food Chemistry,2011,124(3):1223-1230.
[9]
Bu W T,Zheng J,Guo Q J,et al.Ultra-trace plutonium determination in small volume seawater by sector field inductively coupled plasma mass spectrometry with application to Fukushima seawater samples[J].Journal of Chromatography A,2014,1337:171-178.
[10]
Zheng J,Takata H,Tagami K,et al.Rapid determination of total iodine in Japanese coastal seawater using SF-ICP-MS[J].Microchemical Journal,2012,100:42-47.
[11]
Bu W T,Zheng J,Guo Q J,et al.Determination of Pu isotopes in sediment and soil samples by SF-ICP-MS: an improved anion-exchange procedure for Pu separation[J].Journal of Radioanalytical and Nuclear Chemistry, 2017,314(3):2417-2423.
[12]
Dong W,Zheng J,Guo Q J.Particle-size speciation of Pu isotopes in surface soils from Inner Mongolia (China) and its implications for Asian Dust monitoring[J].Applied Radiation and Isotopes,2017,120:133-136.
[13]
Hassan-Loni Y,David K,Larrue S,et al.Uranium quantification of oak tree rings (Quercus petraea) from a former uranium mining site by high resolution inductively coupled plasma mass spectrometry in laser ablation and solution modes[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2019,161:105709.
[14]
Palenova E E,Yudovskaya M A,Frei D,et al.Detrital zircon U-Pb ages of Paleo-to Neoproterozoic black shales of the Baikal-Patom Highlands in Siberia with implications to timing of metamorphism and gold mineralization[J].Journal of Asian Earth Sciences,2019,174:37-58.
[15]
Wu S T,Wörner G,Jochum K P,et al.The preparation and preliminary characterisation of three synthetic andesite reference glass materials (ARM-1,ARM-2, ARM-3) for in situ microanalysis[J].Geostandards and Geoanalytical Research,2019,43(4):567-584.
[16]
冯先进.电感耦合等离子体质谱分析技术在国内矿石矿物分析中的应用[J].冶金分析,2020,40(6):21-36.FENG Xianjin.Application of inductively coupled plasma mass spectrometry for analysis of ore and mineral in China[J].Metallurgical Analysis,2020,40(6):21-36.
[17]
Jakubowski N,Moens L,Vanhaecke E F.Sector field mass spectrometers in ICP-MS [J].Spectrochimica Acta Part B:Atomic Spectroscopy,1998,53:1739-1763.
[18]
Barefoot R R.Determination of platinum group elements and gold in geological materials: a review of recent magnetic sector and laser ablation applications [J].Analytica Chimica Acta,2004,509(2):119-125.
[19]
Zawisza B,Pytlakowska K,Feist B,et al.Determination of rare earth elements by spectroscopic techniques: a review [J].Journal of Analytical Atomic Spectrometry,2011,26:2373-2390
葛丽萍.电感耦合等离子体质谱发展现状[J].盐科学与化工,2019,48(3):9-11.GE Liping.Current development of inductively coupled plasma mass spectrometry[J].Journal of Salt Science and Chemical Industry,2019,48(3):9-11.
[22]
李冰,陆文伟.电感耦合等离子体质谱分析技术[M].北京:中国质检出版社,2017.
[23]
李金英,石磊,鲁盛会,等.电感耦合等离子体质谱(ICP-MS)及其联用技术研究进展[J].中国无机分析化学,2012,2(3):1-5.LI Jinying,SHI Lei,LU Shenghui,et al.Progress of inductively coupled plasma mass apectrometry (ICP-MS) and its hyphenated techniques [J].Chinese Journal of Inorganic Analytical Chemistry,2012,2(3):1-5.
于兆水,陈海杰,张雪梅,等.微波消解-高分辨电感耦合等离子体质谱测定生物样品中55种元素[J]. 物探化探计算技术,2014,36(6):757-762.YU Zhaoshui,CHEN Haijie,ZHANG Xuemei.Determination of 55 kinds of elements in biological sample using high resolution ICP-MS with microwaved digestion[J].Computing Techniques for Geophysical and Geochemical Exploration,2014,36(6):757-762.
[26]
Moldovan M,Krupp E M,Holliday A E,et al.High resolution sector field ICP-MS and multicollector ICP-MS as tools for trace metal speciation in environmental studies:a review[J].Journal of Analytical Atomic Spectrometry,2004,19(7):815-822.
[27]
王学求.勘查地球化学80年来重大事件回顾[J].中国地质,2013,40(1):322-330.WANG Xueqiu.Landmark events of exploration geochemistry in the past 80 years[J].Geology in China,2013,40(1):322-330.
[28]
周国华.多目标区域地球化学调查:分析测试面临的机遇和挑战[J].岩矿测试,2010,29(3):296-300.ZHOU Guohua.Multi-purpose regional geochemical survey:opportunities and challenges for geochemical analysis[J].Rock and Mineral Analysis,2010,29(3):296-300.
[29]
王安齐.多目标地球化学调查样品中41种元素分析方案设计与应用[D].长春:吉林大学,2014.
[30]
李冰,杨红霞.电感耦合等离子体质谱(ICP-MS)技术在地学研究中的应用[J].地学前缘,2003,10(2):367-378.LI Bing,YANG Hongxia.Applications of inductively coupled plasma mass spectrometry in earth science[J]. Earth Science Frontiers,2003,10(2):367-378.
[31]
李冰,何红蓼,史世云,等.痕量元素分析新方法在地质调查中的应用研究进展[J].地质通报,2003,22(2):130-134.LI Bing,HE Hongliao,SHI Shiyun,et al.Recent progress in the study of the application of the new trace element analysis method in geological survey [J].Geological Bulletin of China,2003,22(2):130-134.
[32]
何红蓼,李冰,韩丽荣,等.封闭压力酸溶-ICP-MS法分析地质样品中47个元素的评价[J].分析试验室, 2002,21(5):8-12.HE Hongliao,LI Bing,HAN Lirong,et al.Evaluation of determining 47 elements in geological samples by pressurized acid digestion-ICPMS[J].Chinese Journal of Analysis Laboratory,2002,21(5):8-12.
[33]
Yang Y W,Li C,Liu S,et al.Classification and identification of brands of iron ores using laser-induced breakdown spectroscopy combined with principal component analysis and artificial neural networks[J].Analytical Methods,2020,12(10):1316-1323.
[34]
Liu H,Zhao Q,Guo X,et al.Application of isotopic and elemental fingerprints in identifying the geographical origin of goat milk in China[J].Food Chemistry,2019,277:448-454.
[35]
Zhang W,Hu Z.Recent advances in sample preparation methods for elemental and isotopic analysis of geological samples [J].Spectrochimica Acta Part B:Atomic Spectroscopy,2019,160:1-12.
[36]
Lachas H,Richaud R,Jarvis K E,et al.Determination of 17 trace elements in coal and ash reference materials by ICP-MS applied to milligram sample sizes [J].Analyst,1998,124:177-184.
[37]
Chen S,Wang X H,Niu Y L,et al.Simple and cost-effective methods for precise analysis of trace element abundances in geological materials with ICP-MS [J].Science Bulletin,2017,62(4):277-289.
[38]
Liang Q,Jing H,Gregoire D C.Determination of trace elements in granites by inductively coupled plasma mass spectrometry[J].Talanta,2000,51:507-513.
[39]
胡兆初,高山,柳小明,等.密闭高温高压溶样ICP-MS测定24个国际地质标样中的Sb和Bi [J].光谱学与光谱分析,2007,27(12):2570-2574.HU Zhaochu,GAO Shan,LIU Xiaoming,et al.Determination of Sb and Bi in 24 international geological reference materials by using pressurized acid digestion-ICP-MS[J].Spectroscopy and Spectral Analysis,2007, 27(12):2570-2574.
[40]
Wang J,Nakazato T,Sakanishi K,et al.Microwave digestion with HNO3/H2O2 mixture at high temperatures for determination of trace elements in coal by ICP-OES and ICP-MS[J].Analytica Chimica Acta, 2004,514(1):115-124.
[41]
陈永欣,黎香荣,韦新红,等.微波消解-电感耦合等离子体质谱法测定土壤和沉积物中痕量稀土元素 [J].岩矿测试, 2011,30(5):560-565.CHEN Yongxin,LI Xiangrong,WEI Xinhong,et al.Determination of trace rare earth elements in soils and sediments by inductively coupled plasma-mass spectrometry with microwave digestion[J].Rock and Mineral Analysis,2011,30(5):560-565.
[42]
Meisel M,Schoner N,Paliulionyte V,et al.Determination of rare earth elements Y,Th,Zr,Hf,Nb and Ta in geological reference materials G-2,G-3,SCo-1 and WGB-1 by sodium peroxide sintering and inductively coupled plasma-mass spectrometry[J].Geostandards and Geoanalytical Reasearch,2002,26(1):53-61.
[43]
Ni W S,Zhang H L,Mao X J,et al.Determination of ultra-trace osmium and ruthenium in geological samples by ICP-MS combined with nickel sulfide fire assay pre-concentration and microwave digestion[J].Microchemical Journal,2019,150:1-6.
[44]
He T,Hu Z C,Zhang W,et al.Determination of Cl,Br and I in geological materials by sector field inductively coupled plasma mass spectrometry[J].Anal. Chem.,2019,91(13):8109-8114.
[45]
田梅,韩小元,王江,等.ICP-MS测量环境样品中铀的非质谱干扰内标校正研究[J].分析试验室,2012, 31(8):116-120.TIAN Mei,HAN Xiaoyuan,WANG Jiang,et al.Study on correction of matrix effect with different internal standards during measurement of uranium by ICP-MS[J].Chinese Journal of Analysis Laboratory,2012,31(8): 116-120.
[46]
赵小学,赵宗生,陈纯,等.电感耦合等离子体-质谱法内标元素选择的研究[J].中国环境监测,2016,32(1): 84-87.ZHAO Xiaoxue,ZHAO Zongsheng,CHEN Chun,et al.Study on selection of internal standard element of ICP-MS[J].Environmental Monitoring in China,2016,32(1):84-87.
杨妙峰,刘海波,陈成祥,等.电感耦合等离子体质谱同位素稀释法测定沉积物和茶叶标准物质中铅的研究[J].分析测试学报,2005,24(3):52-55.YANG Miaofeng,LIU Haibo,CHEN Chengxiang,et al.Determination of lead content in standard materials of lake sediment and tea by ID-ICP-MS[J].Journal of Instrumental Analysis,2005,24(3):52-55.
胡净宇,王海舟. ICP-MS中预分离方法的进展[J].冶金分析,2001,21(5):31-35.HU Jingyu,WANG Haizhou.Progress of preseparation methods for ICP-MS[J].Metallurgical Analysis,2001,21(5):31-35.
[51]
张彦辉,张良圣,常阳,等.增压-微波消解电感耦合等离子体质谱法测定含难溶矿物岩石样品中的微量元素[J].铀矿地质,2018,34(2):105-111.ZHANG Yanhui,ZHANG Liangsheng,CHANG Yang,et al.Determining trace elements in rock samples containing refractory minerals by pressurize-microwave inductively coupled plasma mass spectrometry[J].Uranium Geology,2018,34(2):105-111.
[52]
Okina O,Lyapunov S,Avdosyeva M,et al.An investigation of the reliability of HF acid mixtures in the bomb digestion of silicate rocks for the determination of trace elements by ICP-MS[J].Geostandards and Geoanalytical Research,2016,40(4):583-597.
[53]
Okina O I,Lyapunov S M,Dubensky A S.Influence of sample treatment after bomb digestion on determination of trace elements in rock samples by ICP-MS [J].Microchemical Journal,2018,140:123-128.
[54]
Schudel G, Lai V,Gordon K,et al.Trace element characterization of USGS reference materials by HR-ICP-MS and Q-ICP-MS [J].Chemical Geology,2015,410:223-236.
[55]
Willbold M,Jochum K P.Multi-element isotope dilution sector field ICP-MS:a precise technique for the analysis of geological materials and its application to geological reference materials [J].Geostandards and Geoanalytical Research,2005,29(1):63-82.
[56]
Rospabe M,Benoit M,Candaudap F.Determination of trace element mass fractions in ultramafic rocks by HR-ICP-MS:a combined approach using a direct digestion/dilution method and preconcentration by coprecipitation[J]. Geostandards and Geoanalytical Reasearch,2018,42(1):115-129.
[57]
胡圣虹,林守麟,刘勇胜,等.等离子体质谱法测定地质样品中痕量稀土元素的基体效应及多原子离子干扰的校正研究[J].高等学校化学学报,2000,21(3): 368-372.HU Shenghong,LIN Shoulin,LIU Yongsheng,et al.Studies on the calibration of matrix effects and polyatomic ion for rare earth elements in geochemical samples by ICP-MS[J].Chemical Journal of Chinese Universities,2000,21(3):368-372.
[58]
王冠,李华玲,任静,等.高分辨电感耦合等离子体质谱法测定地质样品中稀土元素的氧化物干扰研究 [J].岩矿测试,2013,32(4):561-567.WANG Guan,LI Hualing,REN Jing,et al.Characterization of oxide interference for the determination of rare earth elements in geological samples by high resolution ICP-MS[J].Rock and Mineral Analysis,2013,32(4):561-567.
[59]
白金峰,张勤,孙晓玲,等.高分辨电感耦合等离子体质谱法测定地球化学样品中钪钇和稀土元素[J].岩矿测试,2011,30(1):17-22.BAI Jinfeng,ZHANG Qin,SUN Xiaoling,et al.Determination of Sc,Y and rare earth elements in geochemical samples by high resolution inductively coupled plasma-mass spectrometry[J].Rock and Mineral Analysis,2011,30(1):17-22.
[60]
李华玲,郑荣华,沈加林.基体分离-高分辨电感耦合等离子体质谱法测定硫化物矿石中的稀土元素和钇 [J].分析试验室,2014,33(10):1139-1142.LI Hualing,ZHENG Ronghua,SHEN Jialin.Determination of Y and rare earth elements in sulfide ore by high resolution inductively coupled plasma mass spectrometry after matrix separation[J].Chinese Journal of Analysis Laboratory,2014,33(10):1139-1142.
[61]
Li W J,Jin X D,Gao B Y,et al.Analysis of ultra-low level rare earth elements in magnetite samples from banded iron formations using HR-ICP-MS after chemical separation[J].Analytical Methods,2014,6(15): 6125-6132.
[62]
Li W J,Wang C L,Gao B Y,et al.Determination of multi-element concentrations at ultra-low levels in alternating magnetite and pyrite by HR-ICP-MS using matrix removal and preconcentration[J].Microchemical Journal,2016,127:237-246.
[63]
Varga Z,Katona R,Stefanka Z,et al.Determination of rare-earth elements in uranium-bearing materials by inductively coupled plasma mass spectrometry[J].Talanta,2010,80:1744-1749.
[64]
李华玲,郑荣华,沈加林.高分辨电感耦合等离子体质谱法测定地质样品中的微量锗[J].理化检验(化学分册),2014,50(9):1101-1103.LI Hualing,ZHENG Ronghua,SHEN Jialin.High resolution ICP-MS determination of trace amount of germanium in geological samples [J]. Physical Testing and Chemical Analysis (Part B:Chemical Analysis),2014,50(9):1101-1103.
[65]
Yang G S,Zheng J,Tagami K,et al.Rapid and sensitive determination of tellurium in soil and plant samples by sector-field inductively coupled plasma mass spectrometry [J].Talanta,2013,116:181-187.
