28 September 2026, Volume 46 Issue 9
    

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    Review
  • Jia Yunhai
    Metallurgical Analysis. 2026, 46(9): 1-8. https://doi.org/10.13228/j.boyuan.issn1000-7571.013396
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Ultra-large special-shaped metallic components serve as core base materials for high-end manufacturing sectors including rail transit,marine engineering and energy equipment.Metallurgical defects formed during the fabrication process,such as compositional segregation,non-metallic inclusions and microstructural inhomogeneity,directly determine the mechanical performance and long-term service safety of components.Traditional methods including wet chemical analysis,micro-area characterization and single-point spectroscopic detection suffer from drawbacks such as destructiveness,limited field of view,low efficiency,and inability of full-area assessment,which cannot meet the detection demands of high-throughput,non-destructive,and high-precision quality inspection for large metallic components.Single-spark discharge spectral original position statistic distribution analysis(OPA) technology overcomes the technical bottlenecks of conventional spectral single-point detection by leveraging continuous scanning without pre-burn,single-spark discharge analysis(SDA),and mathematical statistical evaluation.It enables the full-area quantitative characterization of elemental composition distribution within ultra-large size metallic components.It is also an originally and independently developed advanced metallurgical quality assessment technology in China.This paper systematically reviews the fundamental principles and technical framework of OPA technology,summarizes the latest domestic and international advances in spark spectral signal calibration,error compensation and quantitative model optimization,and emphatically highlights its application status and technical advantages in ultra-large engineering metallic components such as high-speed rail wheel axles,large-caliber pipes and high-performance alloy forgings.The aim of this study is to provide systematic theoretical references and technical insights for the iterative upgrading,engineering promotion and formulation of industrial standards for OPA technology.
  • Method Development
  • Zhang Qiaochu, Yuan Liangjing, Jia Yunhai, Yu Lei, Sheng Liang
    Metallurgical Analysis. 2026, 46(9): 9-14. https://doi.org/10.13228/j.boyuan.issn1000-7571.013399
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    The spark discharge original position statistic distribution analysis(OPA) technique enables two-dimensional distribution mapping of elemental composition through continuous scanning excitation over the surface of large size metallic components.A critical step in this process is the accurate reconstruction of discrete spark time-series data into spatially continuous compositional distribution maps,which directly determines the image quality and quantitative accuracy.The traditional data processing methods,such as the direct averaging method,assign the average intensity of all sparks within each excitation spot to every grid cell covered by this spot during the gridding process.Although this approach achieves the conversion from data to spatial representation,it also eliminates the inherent statistical fluctuations of spark signals and alters the statistical distribution characteristics of the original data,resulting in the regular blocky checkerboard artifacts in the images.In this study,based on the physical principle of spark discharge(the landing position of each single spark within the excitation spot is random and independent,and the single spark intensity signal follows statistical fluctuation laws),a random mapping gridding method for data processing was proposed.In this method,the grid step size was naturally determined by hardware parameters including excitation spot diameter,scanning speed,and excitation frequency. Consequently,the number of square grid cells covered by each excitation spot was exactly equal to the number of sparks contained within the spot,realizing the precise one-to-one correspondence and random non-repetitive mapping between spark data and grid cells.Taking the longitudinal section sample of one GCr15 bearing steel continuous casting billet as an example,the proposed method was compared with the direct averaging method,and X-ray fluorescence spectrometry(XRF) scanning images were used as an independent reference for qualitative comparative analysis.The results demonstrated that the compositional distribution images generated by the proposed method were smooth and natural without blocky checkerboard artifacts.The statistical parameters such as the mean value,standard deviation,and segregation degree of elements after processing were fully consistent with the original spark data.The results exhibited consistent banded distribution trend in macro-segregation morphology compared with the XRF images.The proposed method provided a standardized data reconstruction scheme for OPA technology that conformed to physical reality and maintained statistical fidelity.
  • Zhang Haoren, Jia Yunhai, Sheng Liang, Zhang Xiaofen Wang Xuehua, Lü Yong, Yang Lixia
    Metallurgical Analysis. 2026, 46(9): 15-22. https://doi.org/10.13228/j.boyuan.issn1000-7571.013322
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    Original position statistic distribution analysis technique(OPA) has the advantages in the quantitative analysis of elements in metallurgical field,including high accuracy,simultaneous determination of multi-elements,and a well-established system of certified reference materials.Nevertheless,the systematic errors caused by spectral intensity drift and variations in sample surface morphology severely compromise the accuracy of compositional distribution images.In this study,based on a self-developed original position analyzer for large size metal component,a joint correction algorithm for raw surface scanning data was proposed using the cross-section of low-alloy steel ingot as the research object.Firstly,the measured data were constructed into a matrix,and row-column bidirectional linear correction was implemented to eliminate the overall drift trend along the scanning direction and the direction perpendicular to scanning.Subsequently,an adaptive-window Hampel filter was introduced to identify and correct the abnormal data rows by dynamically adjusting the filtering intensity according to the fluctuation levels among scanning rows.The experimental results demonstrated that the segregation of C,Si,Mn,Cr and Mo became more distinct after correction.The elemental contents extracted from corrected contour maps were compared with the measurements acquired via spark discharge atomic emission spectrometry(Spark-OES) at same position,and the maximum relative deviation absolute value was 3.38%,which validated the accuracy of proposed correction strategy.This work provided a systematic,reliable,and accurate data processing workflow for original position analyzer for large size metal component,which facilitated the practical application of this technique in macro-segregation characterization.
  • Applications
  • Han Zhongbao, Yu Feng, Li Dazhao, Liu Jigang, Sheng Liang, Cao Wenquan
    Metallurgical Analysis. 2026, 46(9): 23-33. https://doi.org/10.13228/j.boyuan.issn1000-7571.013398
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    Composition segregation is a critical factor influencing the quality of large-section continuous casting bloom of GCr15 bearing steel.The conventional segregation characterization methods suffer from poor sampling representativeness and discontinuous information.In contrast,the original position analysis technique for metal enables non-destructive acquisition of continuous composition distribution across the full section,realizing the comprehensive and accurate quantitative evaluation of composition segregation.In this study,a fully automated ultra-large size metal original position analysis(OPA) method was employed to conduct full cross-sectional scanning of a 390 mm × 510 mm bloom produced via continuous casting,achieving simultaneous quantitative characterization of composition segregation and carbides.The results indicated that C and Cr were the primary segregating elements,with maximum positive segregation degree of 11.9% and 8.9%,and the statistic fitting degree was 77.4% and 72.9%, respectively.At the position of r/2 (r is the radius),the maximum positive deviation and maximum negative deviation of C was 0.074 1% and -0.036 8%,respectively.The maximum negative deviation of Cr reached -0.074 2%.The eutectic carbides were predominantly concentrated in the central segregation zone,with a total of 42 449 abnormal sparks and a relative content of 68.4 μg/g.The metallographic statistics of continuous casting bloom and chemical analysis results of C showed that the maximum average area and maximum average equivalent diameter of carbides in the central zone were 5 371 μm2 and 82.69 μm,respectively.The carbon segregation index ranged from 0.95 to 1.05,which was consistent with the testing results of OPA.This study verified the advantages of metal OPA technique in the full-section quantitative characterization of large-section continuous casting bloom.It provided essential guidance for the segregation control of GCr15 bearing steel and the improvement of carbide homogeneity.
  • Zhang Xiuxin, Sheng Liang, Min Yanfei, Wu Xiaohan, Zhang Xiaofen, Jia Yunhai
    Metallurgical Analysis. 2026, 46(9): 34-40. https://doi.org/10.13228/j.boyuan.issn1000-7571.013345
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    The segregation degree of elements in Monel K-500 corrosion-resistant alloy has a direct impact on its mechanical properties and microstructural uniformity.Nevertheless,the conventional detection methods based on standard sampling positions can hardly fully reveal the full-area composition distribution of each element in the specimen,and fail to realize the assessment of homogeneity.In this study,a new criterion for segregation evaluation was proposed based on the national standard GB/T 222-2025,and it was applied to the segregation assessment of Monel K-500 corrosion-resistant alloy by combining with the original position statistic distribution analysis technique for large size metal component.The ratio of the permissible deviation specified in the standard to the content was defined as the segregation degree(Ds),and a formula for the upper limit of the segregation degree Ds(max) was established through logarithmic linear fitting.Moreover,the two-dimensional compositional distribution information of 9 elements,including C,Si,Mn,P,S,Fe,Cu,Ti,and Al,was obtained by original position statistic distribution analysis technique for large size metal component.The results showed that all elements were uniformly distributed across the sample cross-section.Both positive and negative segregation degrees of all elements were lower than Ds(max),and no obvious segregation phenomena were observed.The segregation degree characterization method and evaluation model established in this study was applicable for the quality control and assessment of wrought corrosion-resistant alloys such as Monel K-500.
  • Sheng Liang, Jia Yunhai, Zhang Xiaofen, Zhang Haoren Wang Xuehua, Lü Yong, Cheng Peifeng, Yang Lixia
    Metallurgical Analysis. 2026, 46(9): 41-53. https://doi.org/10.13228/j.boyuan.issn1000-7571.013330
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    To address the difficulty of achieving full-section and quantitative characterization of non-metallic inclusions over the large size range of high-speed train wheels,a high-throughput analytical method based on original position statistical distribution analysis,namely the generalized Pareto after normal distribution(GPAND) method,was proposed in this study.Based on single-spark spectrometric original position statistical distribution analysis technique,this method constructed a composite model combining normal function and generalized Pareto distribution(GPD) to perform peak deconvolution of the relative frequency distribution of spectral intensity,thereby effectively separating solid-solution signals from inclusion signals.Scanning electron microscope(SEM) and extreme value theory were further combined to establish a quantitative correlation between the equivalent circle diameter(ECD) of inclusions and spectral intensity.Accordingly,quantitative and statistical distribution characterizations of key parameters including spatial location and size of inclusions in ultra-large wheel steel were realized.The GPAND method was applied to the analysis of two high-speed railway wheels (W1 and W2 manufactured by two different suppliers).Al-bearing inclusions and MnS inclusions in the hub and rim regions were detected,respectively.The results revealed that W1 contained fewer Al-bearing inclusions but more MnS inclusions compared with W2,whereas the total number of MnS inclusions was higher.Particularly in the rim region,although W1 possessed more Al-bearing inclusions with size smaller than 3 μm,the amount of large-sized brittle Al-bearing inclusions was less.This characteristic was highly consistent with the special smelting process adopted for the W1 wheel,which facilitated the effective encapsulation of Al-bearing inclusions by MnS.The conventional analytical techniques can only obtain macroscopic statistical results within limited test zones and fail to acquire full-area spatial distribution and size distribution information of inclusions.The GPAND method addressed the above limitations.It not only improved the quality evaluation system for wheel inclusions,but also provided reliable experimental and theoretical support for service safety assessment,smelting process optimization and inclusion control of high-speed railway wheels.Furthermore,this method could be also extended to cleanliness evaluation and process verification of other high-end steel and alloy components.
  • Wang Xuehua, Zhang Xiuxin, Lü Yong, Zhang Haoren Sheng Liang, Yu Lei, Yang Lixia, Jia Yunhai
    Metallurgical Analysis. 2026, 46(9): 54-62. https://doi.org/10.13228/j.boyuan.issn1000-7571.013331
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    The testing and characterization of full-area compositional segregation degree for large size metal component are critical to guarantee the stability of their service performance.The segregation degree(Ds) is influenced not only by the element content in the metal,but also by the component dimension.Previous studies mainly focused merely on the elemental content anlysis,which was not comprehensive.In this study,the macro-segregation of metal component was characterized and evaluated from two perspectives,i.e.,both elemental content(C) and cross-sectional area(S),which better conformed to practical industrial production.On the basis of data specified in the newly revised national and international standards governing permissible deviation for chemical composition of steel products,including GB/T 222-2025,JIS G 0321-2017 and ASTM A29/A29M-23,a logarithmic function correlating the segregation degree with elemental content and cross-sectional area for non-alloy and low-alloy steels was derived in this paper for the first time:lg Ds=-0.255 1×lg C+0.234 2×lg S—2.346 9.Moreover,the formula for the upper limit of segregation degree(Ds(max)) of non-alloy and low-alloy steels under different contents and cross-sectional areas was established:Ds(max)=0.843 4C-0.255 1S0.234 2.By combing the original position statistic distribution analysis(OPA) technique for large size metal materials,two pieces of 300M low-alloy steel samples with cross-sectional area of 61 544 mm2 and 113 354 mm2 were tested and evaluated,respectively.The maximum segregation degrees of both samples were below the corresponding upper limit of segregation degree,indicating that the macro-segregation met the requirement.
  • Li Baibing, Wang Haizhou, Zhao Lei, Miao Yingqi, Han Junzhe, Jia Yunhai
    Metallurgical Analysis. 2026, 46(9): 63-75. https://doi.org/10.13228/j.boyuan.issn1000-7571.013344
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    C91 heat-resistant steel is widely used for critical components of supercritical and ultra-supercritical thermal power plants due to its excellent high-temperature performance.The compositional homogeneity of large size components directly affects their service life and safety.In this study,the spark mapping analysis for large samples(SMALS) technique was employed to conduct a systematic analysis of composition distribution in C91 heat-resistant steel.First,the optimal experimental conditions for SMALS analysis of C91 heat-resistant steel were determined through orthogonal tests and Z-score normalized statistical analysis:spark excitation frequency of 700 Hz,energy parameter of 0.1 J,electrode spacing of 4.0 mm,tungsten electrode taper of 75°,and argon flow rate of 8 L/min.It was confirmed that spark excitation frequency,energy parameter and electrode spacing served as the dominant factors affecting analytical performance.Second,a partitioned area statistical method based on circular ring segmentation was established for large size ring/billet samples.The evaluation indicators,including positive segregation degree,negative segregation degree and statistic fitting degree,were successfully applied to different subregions of sample A,whereby the areas with positive and negative segregation were clearly delineated.Sample A was a typical C91 heat-resistant steel specimen featuring remarkable macro-segregation.It was employed to establish and verify the partitioned area statistical analytical method and served as a methodological demonstration case.Finally,the optimized method and partitioned area statistical strategy were applied to the analysis of C91 heat-resistant steel billet and steel pipe samples.The results indicated that the compositional homogeneity of steel tubes(finished tubes) was superior to that of round billets(tube billets),and the piercing and rolling process were helpful to improve the macroscopic segregation.The compositional homogeneity of the billet head was inferior to that of the bottom,and there was significant element enrichment in the riser region.The SMALS full-process analysis method established in this study provided a comprehensive and reliable technical solution for the quality evaluation and metallurgical process optimization of large size components made of C91 heat-resistant steel.
  • Song Zufeng, Guo Shiguang, Wang Zhongle, Shen Chang, Guo Junbo, Yu Lei
    Metallurgical Analysis. 2026, 46(9): 76-82. https://doi.org/10.13228/j.boyuan.issn1000-7571.013362
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    The homogeneity of element distribution,occurrence state of non-metallic inclusions and the level of micro-segregation are core indicators to evaluate the quality and service safety of high-speed railway wheel steel round billets.Aiming at the shortcomings of traditional off-line sampling inspection,including narrow test coverage,detection lag,destructive sampling and inability to realize full-area precise quality control of large size round billets,the original position analysis(OPA) techniqge for ultra-large metal component was introduced to construct a non-destructive full-section quality evaluation system for D2-grade high-speed railway wheel steel round billets with an ultra-large cross-section of 450 mm.The original position analyzer for ultra-large metal components were employed to conduct the full-section microstructure quality characterizations,and the comparative verification tests were carried out with traditional wet composition analysis and macroscopic acid etching inspection methods.The results showed that the OPA technique for ultra-large metal components achieved a relative bias(RB) of less than 2% and a relative standard deviation(RSD) of less than 0.3% for elemental detection.The detection accuracy could meet the metallurgical inspection specifications.The statistical homogeneity of elements in the tested D2 high-speed railway wheel steel round billet was not less than 97.1%,indicating excellent compositional homogeneity.Only controllable slight annular ingot segregation and minor central solute segregation were observed without harmful micro-defects.The non-metallic inclusions in steel were dominated by dispersed micron-sized plastic MnS inclusions with an extremely low content of hard harmful inclusions,demonstrating good cleanliness of the steel matrix.Compared with the traditional detection methods,the OPA technique for ultra-large metal components significantly improved detection efficiency and enabled non-destructive,rapid and full-area quality inspection of large-section high-speed railway wheel steel round billets.This technique effectively compensated for the deficiencies of conventional detection means,and provided technical support for continuous casting process optimization of high-speed railway wheel steel,precise control of micro-quality,and intelligent upgrading of high-end steel quality control systems.
  • Jiang Fan, Li Dongling, Li Fulin, Liang Wanying, Wang Haizhou
    Metallurgical Analysis. 2026, 46(9): 83-92. https://doi.org/10.13228/j.boyuan.issn1000-7571.013392
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    In this study,the full-process evolution of integrated disk-shaft forging of the new-generation wrought GH4198 superalloy was systematically investigated by employing the advanced characterization techniques including microbeam X-ray fluorescence spectrometry(μ-XRF),high-throughput scanning electron microscope(SEM),and nanoindentation.The elemental segregation behavior at various processing stages was explored.The results revealed that Co and Cr maintained relatively uniform distribution throughout the whole process,while Nb,Ta and Ti exhibited severe segregation.The growth of columnar crystals during ingot casting was a critical cause of elemental segregation.Homogenization annealing could effectively mitigate the elemental segregation.Nevertheless,the carbide enrichment emerged at the edge of the shaft section of the final forging due to die forging,which induced abnormal segregation of Nb,Ta and Ti.The microstructural characterization demonstrated that the as-cast ingot contained coarse grains.A large amount of primary γ′ precipitates formed after homogenization annealing,which effectively inhibited the grain growth,and the final forging exhibited a uniform grain size distribution with Grade 9.In terms of carbide evolution,the homogenization annealing promoted the transformation of metastable skeleton-like MC-type carbides into stable granular carbides and markedly reduced the carbide size.The three-dimensional(3D) forging further decreased the total area of carbides via hot deformation stress.However,the carbide enrichment was caused during die forging due to the complex die configuration,which had certain impact on the sample homogeneity.In terms of mechanical properties,the standard deviation of hardness decreased gradually with process,and the homogeneity of material was continuously improved.The hardness decreased after homogenization annealing,and then rose significantly at the 3D-forged forging blank and final forging stages owing to grain refinement and dislocation strengthening.This study provided systematic experimental basis for establishing the full-process correlation of process-composition-microstructure-property for GH4198 superalloy,and it also provided theoretical support for forging process optimization and service stability improvement of turbine disks.
  • Microscopic Array Analysis of Inclusion in Large Size Samples
  • Zhang Xiaofen, Jia Yunhai, Lü Yong, Sheng Liang Cheng Peifeng, Zhang Haoren, Wang Xuehua
    Metallurgical Analysis. 2026, 46(9): 93-101. https://doi.org/10.13228/j.boyuan.issn1000-7571.013332
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    Traditional metallographic detection methods based on localized small-area sampling(typically 200 mm2) and manual rating suffer from single-dimensional information,high randomness and poor representativeness.It is difficult to truly reflect the full-field distribution state of inclusions in ultra-large size metallic components.In this study,a microscopic array characterization method for full-field inclusion distribution of ultra-large metallic specimens was established.A multimodal information fusion analysis system was developed,integrating microscopic array parallel acquisition,intelligent online identification and in-situ compositional identification via laser-induced breakdown spectroscopy(LIBS).The system enabled the correlated acquisition of multiple information including inclusion morphology,spatial position and chemical composition in a single scanning run.The full-field detection area for a single sample reached 700 mm×400 mm,and the full-field scanning and data analysis process could be completed within 3 h.The proposed method was applied to the full-field inclusion distribution characterization of a domestic D2-grade high-speed train wheel billet(the analysis area was approximately 380 mm×230 mm),intuitively revealing the field severity and distribution patterns of type A(sulfide),type B(alumina),and type D(globular oxide) inclusions at the inner and outer arcs of the billet.The worst field-of-view rating for type A inclusions reached grade 2.0(total length 449 μm),the worst field-of-view rating for type B inclusions reached grade 1.5(total length 91 μm),while the worst field-of-view rating for type D inclusions was grade 1.0.The proposed method realized the rapid,accurate and full-field characterization of inclusions in ultra-large size metallic samples,and it provided reliable technical means and data support for cleanliness evaluation and process optimization of critical components such as high-speed railway wheels.
  • Lü Yong, Jia Yunhai, Wang Xuehua, Cheng Peifeng, Zhang Xiaofen Zhang Haoren, Sheng Liang
    Metallurgical Analysis. 2026, 46(9): 102-109. https://doi.org/10.13228/j.boyuan.issn1000-7571.013329
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    The size,type,quantity,and spatial distribution of inclusions are core factors determining the fatigue life of high-end metallic structural components.The traditional small-area metallographic methods can hardly reflect the inclusion heterogeneity across the full-section of large forgings,and are prone to miss the local high-risk regions.In this study,targeting aviation-grade 300M steel forgings,a large size metallographic specimen was prepared along the longitudinal section,and optical images were automatically acquired using a 24-unit microscopic array imaging system.To construct a high-precision recognition model,the inclusion types were first labeled on small size metallographic samples by scanning electron microscope and energy dispersive spectroscope(SEM/EDS),and a training dataset was built in combination with data augmentation.Based on the YOLOv11 framework,an inclusion detection model was trained using a transfer learning coupled with incremental optimization strategy,and the recognition results were verified by in-situ compositional validation via laser-induced breakdown spectroscopy(LIBS).The accuracy was approximately 93%. The ultra-large size microscopic array analysis technique was applied to perform fully automatic optical microscopic imaging(25 600 images),machine learning recognition,and laser spectral verification on the longitudinal section of the aviation 300M steel forging (442 mm×221 mm,approximately 97 682 mm2).A total of 29 943 non-metallic inclusions were identified,of which 89.784% were concentrated in the size range of [10,30) μm,and only 4 inclusions(0.013%) were larger than 50 μm.The inclusions were predominantly type A sulfides (22 334 inclusions,74.59%),while type B alumina inclusions were the fewest(474 inclusions,1.58%).A total of 182 995 fields were rated according to method D of ASTM E45,revealing 7 fields with a severity level of 1.0 for the type A heavy series inclusions,2 fields with a severity level of 1.0 for both type C and type D heavy series inclusions.This paper revealed the spatial heterogeneity of inclusions in large forgings,identified localized high-density type A sulfide inclusions regions as major quality risk points,and proposed process optimization suggestions.This study provided a new technical approach for the full-section characterization of inclusions in high-reliability large metal components.