Recovery method of cobalt from cobalt converter slag and its application

GUO Yan-hua, DAI Hui-xin, YANG Jun-long

Metallurgical Analysis ›› 2013, Vol. 33 ›› Issue (5) : 76-80.

PDF(780 KB)
PDF(780 KB)
Metallurgical Analysis ›› 2013, Vol. 33 ›› Issue (5) : 76-80.

Recovery method of cobalt from cobalt converter slag and its application

Author information +
History +

Abstract

In order to realize the comprehensive utilization of cobalt resource, a review was introduced on the recovery method of cobalt from the cobalt converter slag and its research progress and application. During the smelting, most cobalt was chemically dissolved in the converter slag.On the basis of its dissolved and present status in converter slag, the flotation, pyrometallurgy, wet separation, extraction, bioleaching separation and recovery methods were introduced. The advantage and limit of various separation and recovery methods were also discussed. Among them, both the solvent extraction which is characterized by high selectivity, high recovery rate, simple flow, continuous operation and easy to realize automation, and the microbial leaching which is characterized by smallest pollution, low cost and high efficiency have promising application future.

Key words

cobalt / recovery / converter slag / pyrometallurgy / hydrometallurgy / extraction / microbial leaching

Cite this article

Download Citations
GUO Yan-hua, DAI Hui-xin, YANG Jun-long. Recovery method of cobalt from cobalt converter slag and its application[J]. Metallurgical Analysis, 2013, 33(5): 76-80

References

[1] 曹异生. 世界钴工业现状及前景展望[J]. 矿产资源(Mineral Resources),2007, 42; 30-34.
[2] 潘彤. 我国钴矿产资源及其成矿作用[J]. 矿产与地质(Mineral Resources and Geology), 2003, 17(4); 516-517.
[3] 孙晓刚. 世界钴资源的分布和应用[J]. 有色金属(Non-ferrous Metal), 2000, (1); 38-41.
[4] 罗为艾. 钴资源及其市场[J]. 湖南有色金属(Hunan Non-ferrous Metal), 1998, 14(5); 17-20.
[5] 邓彤, 凌云汉. 铜转炉渣中钴的载体矿物在酸解中的行为[J]. 矿物学报(Acta Minalogical Sinica), 2001, (21); 373-376.
[6] Jones R T, Deney A C. Using a direct current arc furnace to recover cobalt from slag[J]. Matals, 1998, 50(10); 57-61.
[7] Jone P, Hayman D, Denton G M. Recovery of cobalt, nickel and Copper from slages using D C- Arc furnace technology[C]. The International Symposium on Challenges of Process Intensisification.Montreal, Canada; CIM, 1996; 214-225.
[8] 赵丽馨.含铜、镍、钴渣的综合利用[J]. 矿产保护与利用(Conservation and Utilization of Mineral Resources),1997(1);31-32.
[9] 童雄, 张林, 同森. 综合回收有色金属物料中的伴生钴的研究概况[J]. 云南冶金(Yunnan Metallurgy), 2001, 30(3);112-17.
[10] 喻正军. 从镍转炉渣中回收钴镍铜的理论与技术研究[D]. 长沙;中南大学, 2007.
[11] 郑雅杰, 陈白珍, 龚竹青, 等. 硫铁矿烧渣制备聚合硫酸铁新工艺[J]. 中南大学学报(Journal of Central South University), 2001, 32(2); 142-145.
[12] Ercan Acma. The effect of Sulfur and reduction temperature on cobalt dissolution during sulfuric acid leaehing of Metallic matte[J]. Cannadian Metallurgical Quarterly,1997,36(1);25-29.
[13] 乐毅,陈述文,陈启平. 铁矿石制备还原铁粉的碳还原过程的实验研究[J]. 矿冶工程(Mining and Metallurgical Engineering), 2003, 23(4); 5l-53.
[14] 许斌,庄剑鸣,白国华,等. 硫酸烧渣综合利用新工艺[J]. 中南大学学报(Journal of Central South University), 2000, 3(3); 215-218.
[15] Xiu-Jing ZHAI, Nai-Jun LI, Xu ZHANG, et al. Recovery of cobalt from coverter slag of chambishi.Copper smelter using reduction smelting process[J]. Transactions of Noferrous Metals Society of China, 2011, 21(9); 2117-2121.
[16] Jandova J, Vu H, Dvorak P. Treatment of sulphate leach liquors to reeover cobalt from waste dusts generated by the glass industry [J]. Hydrometallurgy, 2005, 77(1);67-73.
[17] Rudnik E. Burzynska L. Gumowska W. Hydrometallurgical recovery of copper and cobalt from reduction-roasted copper coverter slag [J]. Minerals Engineering, 2009,22(1);88-95.
[18] Li Y. Papangelakis V G. Peredriy I. High pressure oxidative acid leaching of nickel smelter slag;Characterization of feed and residue [J]. Hydrometallurgy, 2009,97(3-4);185-193.
[19] Baghalha M, Papangelakis V G, Curlook W. Factors affecting the leachability of Ni/Co/Cu slags at high temperature [J]. Hydrometallurgy, 2007,85(1);42-52.
[20] Anand Rao K, Natarajan R, Padmanbhan N P H. Studies on recovery of copper, nickel, cobalt and molybdenum values from a bulk sulphide concentrate of an Indian uranium ore[J]. Hydrometallurgy, 2001, 62(1); 115-124.
[21] 何淑琴. 堆浸提铜技术的发展趋势[J]. 国外金属矿选矿(Metallic Ore Dressing Abroad), 1998(2); 21-26.
[22] 夏光祥, 涂桃枝,石伟,等. 氨氰法从铜金矿石中提金研究与工业实践[J]. 黄金(Gold), 1995(7);26-29.
[23] 李立元,陈学田. P507萃取剂在钴,镍分离系统中的应用[J]. 世界有色金属(World Nonferrous Metals), 1997, (10);26-28.
[24] 杨智宽,鲍益海. 用萃取法从废钴渣中回收钴. 环境污染与防冶(Environmental Pollution and Control), 1995, 17(5);42-44.
[25] 周炳诊. 用P204和P507脱除含钴废料中的杂质生产高纯氯化钴. 有色金属(Non-ferrous Metal),2002,(6);16-17.
[26]包福毅.溶剂萃取在镍钴湿法冶金中应用的进展[J].有色金属;冶炼部分(Non-ferrous Metal; Extractive Metallurgy),1995(2); 12-16.
[27] 兰兴华. 镍和钴溶剂萃取进展[J]. 世界有色金属(World Nonferrous Metals), 2004;35-39.
[28] 温建康,阮仁满. 高砷低硫镍钴硫化矿浸矿菌的选育与生物浸出研究[J]. 稀有金属(Rare Metal), 2007,31(4);537-541.
[29]Zhang G j, Fang Z H. The contribution of direct and indirect aetions in bioleaching of pentlandite[J]. Hydrometallurgy, 2005,50;59.
[30] 何焕华,蔡乔方. 中国镍钴冶金[M].北京;冶金工业出版社,2000.541-557.
[31] 喻正军,冯其明,欧乐明,等. 还原硫化法从镍转炉渣中富集钴镍铜[J]. 矿冶工程(Mining and Metallurgical Engineering), 2006,26(1);49-51.
[32] 崔和涛.镍铜转炉渣电炉贫化制取金属化钴冰铜[J]. 矿冶(Mining and Metallurgical),1997(2);10-19.
[33] 熊昆,徐亚飞,杨大锦. 含钴铜水淬渣还原熔炼综合回收研究 [J]. 有色金属;冶炼部分 (Non-ferrous Metal;Extractive Metallurgy),2009,(3);13-16.
[34] 陈永强,王成彦,王忠. 高硅铜钴矿电炉还原熔炼渣型研究[J]. 有色金属;冶炼部分(Non-ferrous Metal;Extractive Metallurgy),2003(4);23-25.
[35] 廖春发,邓佐国. 从铜铁钴合金渣中制取氧化钴工艺的研究[J]. 江西有色金属(Jiangxi Non-ferrous Metal), 1999, 13(2);1-6.
[36] 谌可颂. 从废弃炉渣中回收钴、镍、铜的研究[J]. 湖南有色金属(Huan Non-ferrous Metal), 2006,22(6);24-29.
[37] 何家成. 氨法回收人造金刚石酸洗废液中的镍、钴、锰[J]. 中国物资再生(China National Resources Recycling),1997(6);10-12.
[38] 谢福标. 钴原料中有价元素综合回收的生产实践[J]. 矿冶(Mining and Metallurgical),2001,10(3);61-74.
[39] 喻正军,冯其明,欧乐明,等. 常压下硫酸体系中钴冰铜的浸出[J]. 中南大学学报;自然科学版(Journal of Central South University; Natural Science),2006, 37(4);675-679.
[40] 蒋金龙, 江模辉. 一种含钴废矿渣的生物浸出初步研究. 矿产资源综合利用(Comprehensive Utilization of Mineral Resources),2003,(1);42-45.
[41] 杨松荣,邱冠周,谢纪元,等. 国外生物氧化提取技术的进展[J]. 有色金属(Non-ferrous Metal), 2001,53(3);84-87.
PDF(780 KB)

4

Accesses

0

Citation

Detail

Sections
Recommended

/