Abstract：In recent years, spark discharge atomic emission spectrometry has been widely used as a quality control method in the production process of welding materials. As a technology for the analysis of sample surface, however, the proposed method has both advantages and disadvantages in the field of welding materials. It summarized the application status of spark discharge atomic emission spectrometry in the analysis of welding materials with several different shapes. The development and application of spark discharge atomic emission spectrometry in analyzing welding materials with different matrix, different kinds of elements and various analysis functions were discussed. Moreover, the quality control measures in analyzing welding materials by spark discharge atomic emission spectrometry was summarized. Finally, it pointed out that the analysis of small-size welding wire and welding strip was the bottleneck of proposed method in analyzing welding materials, which was also the major problem in the development of spark discharge atomic emission spectrometry to analyze welding materials in the future.
[1] 张勇,贾云海,陈吉文,等.激光诱导击穿光谱在材料表面分析领域中的应用进展[J].光谱学与光谱分析,2012,32(6):1441-1446. ZHANG Yong,JIA Yunhai,CHEN Jiwen,et al.Applica-tion progress of laser-induced breakdown spectroscopy for suiface analysis in materials science field[J].Spectroscopy and Spectral Analysis,2012,32(6):1441-1446. [2] 刘攀,常国梁,张欣耀,等.我国焊接药剂化学分析标准体系现状与发展[J].冶金分析,2020,40(11):8-16. LIU Pan,CHANG Guoliang,ZHANG Xinyao,et al.Status and development of standard system for chemical analysis of welding flux in China[J].Metallurgical Analysis,2020,40(11):8-16. [3] 中华人民共和国国家质量监督检验检疫总局.GB/T 14203—2016火花放电原子发射光谱分析法通则[S].北京:中国标准出版社,2016. [4] 张教赟,张忠和.直读光谱法测定实芯焊丝的操作技巧[J].理化检验(化学分册),2014,50(2):900-902. ZHANG Jiaoyun,ZHANG Zhonghe.Operation skills of direct-reading spectrometry for measuring solid core welding wire[J].Physical Testing and Chemical Analysis(Part B:Chemical Analysis),2014,50(2):900-902. [5] 黄河,王萍,刘艳杰. 采用直读光谱仪分析1.2 mm碳钢焊丝成分的研究[J].工程与试验,2012,52(2):49-52. HUANG He,WANG Ping,LIU Yanjie.Study on composi-tion analysis of 1.2 mm carbon steel welding wire by direct reading spectrometer[J].Engineering and Testing,2012,52(2):49-52. [6] 艾生炳,郭世永,李晓勇,等.火花源光谱法分析ø0.8 mm细焊丝的试验研究[J].冶金分析,2001,21(4):50-52. AI Shengbing,GUO Shiyong,LI Xiaoyong,et al.Study on the analysis of ø 0.8 mm thin welding wires by spark source spectrometry[J].Metallurgical Analysis,2001,21(4):50-52. [7] 陈俊义.直读光谱法直接测定ER-70G焊丝中铬、镍、钼、钛、铜[J].科学中国人,2014,3(3):8. CHEN Junyi.Direct determination of chromium, nickel, molybdenum, titanium and copper in ER-70G welding wire by direct-reading spectrometry[J].Scientific Chine-se,2014,3(3):8. [8] 王娇娜,周西林,王亚森,等.冷压塑形制样-光电直读光谱法测定碳素钢钢丝中C、Si、Mn、P、S、Cr、Ni、Cu的含量[J].理化检验(化学分册),2019,55(9):1107-1111. WANG Jiaona,ZHOU Xilin,WANG Yasen,et al.Photoelectric direct-reading spectroscopy determination of C,Si,Mn,S,P,Cr,Ni and Cu in carbon steel wire prepared by cold pressure moulding[J].Physical Testing and Chemical Analysis(Part B:Chemical Analysis),2019,55(9):1107-1111. [9] 邹莉莎,张华.光电直读光谱法测定埋弧焊丝化学成分[J].理化检验(化学分册),2011,47(5):611-623. ZOU Lisha,ZHANG Hua.Determination of chemical composition of submerged arc welding wire by photoelectric direct-reading spectrometry[J].Physical Testing and Chemical Analysis(Part B:Chemical Analysis),2011,47(5):611-623. [10] 刘满雨,冯伟,王国佛,等.火花放电原子发射光谱分析中不同规格线材类型标准化样品兼容性探讨[J].冶金分析,2021,41(9):18-23. LIU Manyu,FENG Wei,WANG Guofu,et al.Discussion on the compatibility of type standardized samples of wire rod with different specifications in spark discharge atomic emission spectrometric ananlysis[J].Metallurgical Analysis,2021,41(9):18-23. [11] 刘信文,牛红梅.样品温度对火花源原子发射光谱分析准确度影响的研究[J].冶金分析,2010,30(增):258-264. LIU Xinwen,NIU Hongmei.Investigation on sample temperature affecting the accuracy of spark source atomic emission spectrometry analysis[J].Metallurgical Analysis,2010,30(Supplement):258-264. [12] 中华人民共和国国家质量监督检验检疫总局.GB/T 4336—2016 碳素钢和中低合金钢 多元素含量的测定 火花放电原子发射光谱法(常规法)[S].北京:中国标准出版社,2016. [13] 中华人民共和国国家质量监督检验检疫总局.GB/T 11170—2008 不锈钢 多元素含量的测定 火花放电原子发射光谱法(常规法)[S].北京:中国标准出版社,2008. [14] 中华人民共和国国家质量监督检验检疫总局.GB/T 38939—2020 镍基合金 多元素含量的测定 火花放电原子发射光谱法(常规法)[S].北京:中国标准出版社,2020. [15] 李千.火花直读光谱法测定不锈钢焊带中9种元素含量[J].中国重型装备,2016,6(2):43-45. LI Qian.Determination of nine elements contents in stainless steel welding strip by spark direct-reading spectrometric method[J].China Heavy Equipment,2016,6(2):43-45. [16] 洪泽浩,蔡锐波.光电直读光谱法测定不锈钢薄板中7种元素含量[J].理化检验(化学分册),2013,49(5):177-182. HONG Zehao,CAI Ruibo.Determination of seven elements in stainless steel sheet by photoelectric direct-reading spectrometry[J].Physical Testing and Chemical Analysis(Part B:Chemical Analysis),2013,49(5):177-182. [17] 杨建菊,张东文.直读光谱仪及其在电力系统中的应用[J].河北电力技术,2006,25(2):27-30. YANG Jianju,ZHANG Dongwen.Direct reading spectrometer and its application in power system[J].Hebei Electric Power,2006,25(2):27-30. [18] 刘满雨.不锈钢带极堆焊层化学成分梯度分布规律及性能的研究[D].哈尔滨:哈尔滨工业大学,2017. [19] 贾云海,王向红.光电直读光谱法测定纯金属中的痕量元素[J].光谱学与光谱分析,2000,20(4):518-521. JIA Yunhai,WANG Xianghong.Determination of trace elements in pure metal by optical emission spectrometry [J].Spectroscopy and Spectral Analysis, 2000,20(4):518-521. [20] 朵云琨,邓勇.直读光谱法测定无铅焊料中的铅、镉、铜、银、铋、砷、锑和铁[J].光谱实验室,2012,29(6):3649-3652. DUO Yunkun,DENG Yong.Determination of Pb, Cd, Cu, Ag, Bi, As, Sb and Fe in lead-free solder by direct-reading spectrometry[J].Chinese Journal of Spectr-oscopy Laboratory,2012,29(6):3469-3652. [21] 廖雅倩.钢铁元素分析方法与样品状态适用性探讨[J].铸造设备与工艺,2021,3(6):42-62. LIAO Yaqian.Discussion on applicability of elemental analysis method and sample state in iron and steel[J].Foundry Equipment & Technology,2021,3(6):42-62. [22] 刘辉,张春晓,胡军,等.火花源原子发射光谱法测定NiFeCr合金中氮[J].冶金分析,2012,32(6):10-13. LIU Hui,ZHANG Chunxiao,HU Jun,et al.Determination of nitrogen in NiFeCr alloy by optical emission spectrometry[J].Metallurgical Analysis,2012,32(6):10-13. [23] 任维萍.影响火花源原子发射光谱法测定不锈钢中氮元素精度的因素分析[J].冶金分析,2014,34(8):16-21. REN Weiping.Analysis of factors influencing the determination precision of nitrogen in stainless steel by spark source atomic emission spectrometry[J].Metallurgical Analysis,2014,34(8):16-21. [24] 杨新能,王娟,刁正斌,等.火花源原子发射光谱法测定钢中氮[J].冶金分析,2012,32(4):36-40. YANG Xinneng,WANG Juan,DIAO Zhengbin,et al.Analysis of nitrogen in steel by spark atomic emission spectrometry[J].Metallurgical Analysis, 2012,32(4):36-40. [25] 谢欢.光谱分析钢中氮元素波动因素的探讨和改进[J].福建分析测试,2014,23(2):44-47. XIE Huan.A research of fluctuations in spectral analysis of nitrogen in steel[J].Fujian Analysis & Testing,2014,23(2):44-47. [26] 张存贵.钢中微量氮元素光谱分析技术开发与应用[J].山西冶金,2017(1):19-21. ZHANG Cungui.Development and application of spectrum analysis technology of trace nitrogen in steel[J].Shanxi Metallurgical,2017(1):19-21. [27] 黄子鉴,康宝军,赵竞泽,等.火花源原子发射光谱法测定钢中超低氮[J].冶金分析,2008,28(10):23-26. HUANG Zijian,KANG Baojun,ZHAO Jingze,et al.Determination of ultra-low nitrogen in steel by spark atomic emission spectrometry[J].Metallurgical Analysis,2008,28(10):23-26. [28] 沈克,张兆雄,张昌强,等.火花放电原子发射光谱分析中优先放电成因探讨[J].冶金分析,2016,36(10):1-9. SHEN Ke,ZHANG Zhaoxiong,ZHANG Changqiang,et al.Discussion on the phenomenon of preferential discharge in spark source atomic emission spectrometry [J].Metallurgical Analysis,2016,36(10):1-9. [29] 李冬玲,李美玲,贾云海,等.火花源原子发射光谱法在钢中夹杂物状态分析中的应用[J].冶金分析,2011,31(5):20-26. LI Dongling,LI Meiling,JIA Yunhai,et al.Application of spark source atomic emission spectrometry to the state analysis of inclusions in steel[J].Metallurgical Analysis,2011,31(5):20-26. [30] 沈克,张兆雄,郭芳,等.火花源原子发射光谱法鉴别汽车板表面线状缺陷[J].冶金分析,2015,35(2):1-5. SHEN Ke,ZHANG Zhaoxiong,GUO Fang,et al.Identification of linear defects on automobile steel sheet by spark source atomic emission spectrometry[J].Metall-urgical Analysis,2015,35(2):1-5. [31] 韩丽华,龚宜勇,韩春梅,等.火花源原子发射光谱法测定中低合金钢中酸溶铝[J].冶金分析,2011,31(10):24-28. HAN Lihua,GONG Yiyong,HAN Chunmei,et al. Determination of acid-soluble aluminum in low and medium alloy steel by spark source atomic emission spectrometry[J].Metallurgical Analysis,2011,31(10):24-28. [32] 詹会霞,谷国雪,范瑾.火花放电原子发射光谱法分析低合金钢中酸溶铝的准确性探究[J].冶金分析,2017,37(12):50-54. ZHAN Huixia,GU Guoxue,FAN Jin.Discussion on analytical accuracy of acid soluble aluminum in low alloy steel by spark discharge atomic emission spectrometry [J].Metallurgical Analysis,2017,37(12):50-54. [33] 李健,朱艳玲,王建林.镍基材料火花光谱标准控制样品的研究[J].电站辅机,2011,32(4):39-41. LI Jian,ZHU Yanling,WANG Jianlin.Methods for determinling elements in nickel-based superalloys[J].Power Station Auxiliary Equipment,2011,32(4):39-41. [34] 刘满雨,陈波,王庆江,等.火花放电原子发射光谱法分析铜锌钎料中铜锌锰结果稳定性的探讨[J].冶金分析,2019,39(6):42-48. LIU Manyu,CHEN Bo,WANG Qingjiang,et al.Discussion on the stability of analyzing znic-copper brazing filler metal with the spark discharge atomic emission spectrometry[J].Metallurgical Analysis,2019,39(6):42-48. [35] 周娅,罗舜.光电直读光谱法测定锡铅焊料中九种元素[J].云南冶金,2016,45(2):128-131. ZHOU Ya,LUO Shun.Determination on nine elemen-ts in tin-lead solder by photoelectric direct-reading spe-ctrometer[J].Yunnan Metallurgy,2016,45(2):128-131. [36] 贾云海,孙晓飞.火花放电原子发射光谱分析全流程正确度控制方法研究[J].冶金分析,2020,40(7):1-7. JIA Yunhai,SUN Xiaofei.Study on the control method of the accuracy of the whole process of spark discharge emission spectrum analysis [J].Metallurgical Analysis,2020,40(7):1-7. [37] 刘满雨,冯伟,王纯,等.火花放电原子发射光谱仪分析不锈钢的长期稳定性[J].冶金分析,2021,41(4):34-40. LIU Manyu,FENG Wei,WANG Chun,et al.The long-term stability test of stainless steel analysis by spark discharge atomic emission spectrometer[J].Metallurgical Analysis,2021,41(4):34-40. [38] 刘满雨,冯伟,郑庆铭.质量控制图监视直读光谱仪分析焊接材料稳定性的应用[J].现代科学仪器,2017,34(5):90-94. LIU Manyu,FENG Wei,ZHENG Qingming,et al.Application of quality control chat in monitoring the analysis of welding materials stability of direct reading spectrometer test data[J].Modern Scientific Instruments,2017,34(5):90-94. [39] 钟继志,赖桂珍,陈露芳,等.质量控制图在直读光谱仪检测数据稳定性中的应用[J].广东化工,2018,45(5):49-61. ZHONG Jizhi,LAI Guizhen,CHEN Lufang,et al.Appli-cation of quality control chart in the stability of direct-reading spectrometer test data[J].Guangdong Chemical Industry,2018,45(5):49-61. [40] 蒋威,周青,朱敏星.质量控制图在直读光谱仪检测数据稳定性中的研究与应用[J].中国检验检测,2017,25(3):26-28. JIANG Wei,ZHOU Qing,ZHU Minxing.Research and application of quality control chart in test data stability of direct reading spectrometer[J].China Inspection Body &Testing,2017,25(3):26-28. [41] 郑庆铭,陈波,陈佩寅.火花放电原子发射光谱法分析不锈钢焊材的准确度评定[J].现代科学仪器,2019,36(2):65-68. ZHENG Qingming,CHEN Bo,CHEN Peiyin.The assessment of the direct-reading spectrometer′s accuracy in checking welding materials′quality[J].Modern Scientific Instruments,2019,36(2):65-68. [42] 门生会.火花源原子发射光谱法测定HO8A焊接用钢盘条中碳、硅、锰、磷、硫含量的不确定度评定[J].分析测试技术与仪器,2013,19(4):238-243. MEN Shenghui.Uncertainty evaluation of measurement of carbon,silicon,manganese,phosphorus,sulfur content in HO8A eire rod by spark discharge atomic emission spectrometry[J].Analysis and Test Technology and Instrument,2013,19(4):238-243. [43] 喻振兴,张斌杰,袁峥,等.SPECTRO LAB直读光谱仪的期间核查[J].化学工程与装备,2013(3):164-166. YU Zhenxing,ZHANG Binjie,YUAN Zheng,et al. SPECTRO LAB intermediate verification of direct reading spectrometer[J].Chemical Engineering & Equipment,2013(3):164-166. [44] 高文工,白伟东,郭娟,等.中低合金钢化学成分能力验证样品制备及均匀性检验流程探讨[J].冶金分析,2019,39(1):77-81. GAO Wengong,BAI Weidong,GUO Juan,et al.Preparation of middle-low alloy steel chemical compositon sample for proficiency testing and discussion on homogeneity test procedures[J].Metallurgical Analysis,2019,39(1):77-81. [45] 蒋存林,郭亚平,陈铭舫.光电直读光谱持久曲线法分析低合金钢丝[J].理化检验(化学分册),2005,41(11):812-817. JIANG Cunlin,GUO Yaping,CHEN Mingfang.Using permanent working curve for the direct reading spectroscopic analysis of low alloy steel wires[J].Physical Testing and Chemical Analysis(Part B:Chemical Analysis),2005,41(11):812-817. [46] 刘满雨,李振华,冯伟,等.火花放电原子发射光谱法分析带极堆焊熔敷金属中7种元素[J].冶金分析,2018,38(11):1-6. LIU Manyu,LI Zhenhua,FENG Wei,et al.Determination of seven elements in strip surfacing deposited metal by spark discharge atomic emission spectrometry[J].Metallurgical Analysis,2018,38(11):1-6. [47] 张林,屠勇,陈易新,等.直读光谱分析用焊丝标样研制[J].东方电气评论,2006,20(2):36-38. ZHANG Lin,TU Yong,CHEN Yixin,et al.Development of welding wire standard sample for direct reading spectral analysis[J].Dongfang Electric Review,2006,20(2):36-38.
