Abstract：The spark discharge atomic emission spectrometry is widely used in the routine inspection of strip surfacing deposited metal in actual production process. Due to the differences of factors such as manufacturing technique and structure, the analysis results usually have errors when the standard samples are used as control samples. The determination of seven elements (including carbon, silicon, manganese, sulfur, phosphorus, chromium and nickel) in strip surfacing deposited metal by spark discharge atomic emission spectrometry was investigated. The flush time, pre-combustion time and integral time in the light source parameters were optimized. The following experimental conditions were finally selected: the flush time was 5s, the pre-combustion time was 6s and the integral time was 7s. The influence of two type standardization methods (i.e., using standard sample and self-made control sample) on the analysis results was discussed. It was found that the analysis results of carbon, manganese, chromium and nickel especially chromium had great difference with the chemical wet method when the stainless steel standard sample ZBGS003 was used as standardization sample for the determination of strip surfacing deposited metal. After establishing the type standardization curve with the self-made strip surfacing deposited metal, the determination results were basically consistent with those obtained by the chemical wet analysis method.
刘满雨, 李振华, 冯伟, 魏涛, 杨再勋, 金岩. 火花放电原子发射光谱法分析带极堆焊熔敷金属中7种元素[J]. 冶金分析, 2018, 38(11): 1-6.
LIU Man-yu, LI Zhen-hua, FENG Wei, WEI Tao, YANG Zai-xun, JIN Yan. Determination of seven elements in strip surfacing deposited metal by spark discharge atomic emission spectrometry. , 2018, 38(11): 1-6.
文孟喜,孙晓飞,贾云海.火花放电原子发射光谱测定镍基合金中铁元素的校准曲线探讨[J].冶金分析,2018,38(2):9-17.WEN Meng-xi,SUN Xiao-fei,JIA Yun-hai.Discussion on calibration curve for determination of iron in nickel based alloy by spark discharge atomic emission spectrometry[J].Metallurgical Analysis,2018,38(2):9-17.
芦飞.火花放电原子发射光谱法分析不锈钢中铬镍元素精密度和准确度的影响因素探讨[J].冶金分析,2017,37(10):37-46.LU Fei.Discussion of factors influencing precision and accuracy in determination of chromium and nickel in stainless steel by spark discharge atomic emission spectrometry[J].Metallurgical Analysis,2017,37(10):37-46.
