Abstract：In view of the lack of mature and commercial portable laser-induced breakdown spectroscopy (LIBS) instruments in China, and the poor spectral stability and anti-interference performance of the existing portable LIBS analyzer, a new compact and integrated portable LIBS instrument was developed successfully. With this instrument, the classification of 24 kinds of metallic ores and the accurate quantitative analysis of Cr, Ni, Si, Cu, Ti, and V in microalloy steel samples were achieved successfully. Among them, the average classification accuracy of 24 metallic ores reached 95.83%. The determination coefficient (R2) of the quantitative analysis model of each element reached 0.993, 0.984, 0.996, 0.990, 0.980, and 0.999, the limits of detection (LODs) reached 0.0355%, 0.0587%, 0.0773%, 0.0120%, 0.0085% and 0.0082%, and the average relative error of cross-validations (ARECVs) reached 5.20%, 11.30%, 18.18%, 9.63%, 9.73%, and 9.17%, respectively. The results showed that as-developed instrument had good qualitative and quantitative analysis performance, which provided a new solution for the localization of portable LIBS instruments.
闫久江, 李祥友. 新型便携式激光诱导击穿光谱仪器及其应用研究[J]. 冶金分析, 2020, 40(12): 66-71.
YAN Jiu-jiang, LI Xiang-you. Research on a new portable laser-induced breakdown spectroscopy system and its application. , 2020, 40(12): 66-71.
林庆宇,段忆翔.激光诱导击穿光谱:从实验平台到现场仪器[J].分析化学,2017,45(9):1405-1414.LIN Qing-Yu,DUAN Yi-xiang.Laser-induced breakdown spectroscopy:from experimental platform to field instrument[J].Chinese Journal of Analytical Chemistry,2017,45(9):1405-1414.
[2]
Yamamoto K Y,Cremers D A,Ferris M J,et al.Detection of metals in the environment using a portable laser-induced breakdown spectroscopy instrument[J].Applied Spectroscopy,1996,50(2):222-233.
[3]
李安,邵秋峰,刘瑞斌.新型便携式激光诱导击穿光谱系统综述[J].中国光学,2017,10(4):426-437.LI An,SHAO Qiu-feng,LIU Rui-bin.Review of new type portable laser-induced breakdown spectroscopy system[J].Chinese Optics,2017,10(4):426-437.
[4]
L′Hermite D,Vors E,Vercouter T,et al.Evaluation of the efficacy of a portable LIBS system for detection of CWA on surfaces[J].Environmental Science and Pollution Research,2016,23(9):8219-8226.
[5]
DeLucia F C,Samuels A C,Harmon R S,et al.Laser-induced breakdown spectroscopy (LIBS):a promising versatile chemical sensor technology for hazardous material detection[J].IEEE Sensors Journal,2005,5(4):681-689.
[6]
YAN J,Li S,LIU K,et al.An image features assisted line selection method in laser-induced breakdown spectroscopy[J].Analytica Chimica Acta,2020,1111:139-146.
[7]
曾庆栋,朱志恒,邓凡,等.便携式激光诱导击穿光谱结合小波变换去背景算法定量分析钢铁中Mn元素[J].光子学报,2018,47(8):102-111.ZENG Qing-dong,ZHU Zhi-heng,DENG Fan,et al.Quantitative analyses of element Mn in iron using portable laser-induced breakdown spectroscopy with algorithm of background removal based on wavelet transform[J].Acta Photonica Sinica,2018,47(8):102-111.
[8]
Yan J J,Hao Z Q,Zhou R,et al.A quantitative analysis method assisted by image features in laser-induced breakdown spectroscopy[J].Analytica Chimica Acta,2019,1082:30-36.
[9]
赵书瑞,王华丽,卢孟柯.内标元素强度筛选法在激光诱导击穿光谱定量分析土壤标样中铁钛锶的应用[J].冶金分析,2018,38(7):33-37.ZHAO Shu-rui,WANG Hua-Li,LU Meng-ke.Application of internal standard element intensity-screening in quantitative analysis of iron,titanium and strontium in soil standard sample by laser induced breakdown spectroscopy[J].Metallurgical Analysis,2018,38(7)33-37.
[10]
韩中杰,刘佳,王辉,等.基于激光诱导击穿光谱技术的重轨钢中铝系夹杂物含量分析方法研究[J].冶金分析,2019,39(6):1-6.HAN Zhong-jie,LIU Jia,WANG Hui,et al.Study on analytical method for the content of aluminium inclusions in heavy rail steel by laser-induced breakdown spectroscopy[J].Metallurgical Analysis,2019,39(6):1-6.
