Application progress of laser-induced breakdown spectroscopy in online analysis of metal materials
WANG Ya-wen1,2,3, ZHANG Yong4, CHEN Xiong-fei1,2,3, ZHAO Zhen-yang4, LIU Ying1,2,3, LIU Peng-yu*1,2,3
1. National Analysis and Testing Center of Nonferrous Metals and Electronic Materials, Beijing 100088, China; 2. China United Test & Certification Co., Ltd., Beijing 101400, China; 3. General Research Institute for NonferrousMetals, Beijing 100088, China; 4. Shandong Dongyi Photoelectric Instruments Co., Ltd., Yantai 264670, China
Abstract：Due to the characteristics of no need for sample preparation, fast analysis speed, remote online telemetry, and two-dimensional surface distribution and depth analysis of elements, laser-induced breakdown spectroscopy (LIBS) technique has attracted the attention of researchers in the field of spectrochemical analysis. In the field of metallurgical process control, it was of great significance to realize the online analysis of metal materials and obtain the multi-dimensional information of elements for the real-time monitoring of the production process of metal materials and the accurate realization of the rapid classification of metal materials. Compared with the traditional analysis methods, LIBS technique was considered to be one of the best ways to realize the online analysis of metal materials, and a variety of commercially instruments have been introduced. Online instruments of LIBS was introduced, and the development situation and challenge of LIBS in recent years were discussed as follows: online analysis of molten metals, continuous casting billet identification, online analysis of slag, classification and identification of metal materials, coating analysis of metal materials. Finally, the prospect of LIBS online analysis was presented.
Noll R,Fricke-Begemann C,Connemann S,et al.LIBS analyses for industrial applications-an overview of developments from 2014 to 2018[J].Journal of Analytical Atomic Spectrometry,2018,33(6):945-956.
[2]
Hudson S W,Craparo J,De Saro R,et al.Applications of laser-induced breakdown spectroscopy (LIBS) in molten metal processing[J].Metallurgical and Materials Transactions B,2017,48:2731-2742.
[3]
Harmon R S,Russo R E,Hark R R.Applications of laser-induced breakdown spectroscopy for geochemical and environmental analysis: a comprehensive review[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2013,87:11-26.
[4]
Wallin S,Pettersson A,Östmark H,et al.Laser-based standoff detection of explosives:a critical review[J].Analytical and Bioanalytical Chemistry,2009,395(2):259-274.
[5]
Harmon R S,Lawley C J M,Watts J,et al.Laser-induced breakdown spectroscopy-an emerging analytical tool for mineral exploration[J].Minerals,2019,9(12):718.
[6]
Fabre C.Advances in laser-induced breakdown spectroscopy analysis for geology:a critical review[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2020,166:105799.
[7]
Martin M Z,Allman S,Brice D J,et al.Exploring laser-induced breakdown spectroscopy for nuclear materials analysis and in-situ application[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2012,74:177-183.
[8]
Cousin A,Forni O,Maurice S,et al.Laser induced breakdown spectroscopy library for the Martian environment[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2011,66:805-814.
[9]
Winefordner J D,Gornushkin I B,Correll T,et al.Comparing several atomic spectrometric methods to the super stars:special emphasis on laser induced breakdown spectrometry,LIBS,a future super star[J].Journal of Analytical Atomic Spectrometry,2004,19(9):1061-1083.
[10]
Sallé B,Mauchien P,Maurice S.Laser-induced breakdown spectroscopy in open-path configuration for the analysis of distant objects[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2007,62:739-768.
[11]
Gudmundsson S H,Matthiasson J,Björnsson B M,et al.Quantitative in-situ analysis of impurity elements in primary aluminum rocessing using laser-induced breakdown spectroscopy[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2019,158:105646.
[12]
Sun L,Yu H,Cong Z,et al.In situ analysis of steel melt by double-pulse laser-induced breakdown spectroscopy with a Cassegrain telescope[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2015,112:40-48.
[13]
Zhao T,Li X,Zhong Q,et al.Quantitative analysis of vacuum induction melting by laser-induced breakdown spectroscopy[J].Journal of Visualized Experiments,2019,148:e57903.
[14]
马翠红,王汉炳.LIBS结合自由定标法对钢液中多元素成分定量分析[J].激光杂志,2017,38(11):42-45.MA Cui-hong,WANG Han-bing.Composition quantitative analysis of multiple elements in liquid steel based on LIBS combined with calibration-free method[J].Laser Journal,2017,38(11):42-45.
[15]
崔金龙,马翠红,徐少彬,等.基于自由定标法的LIBS钢液Cr元素和Ni元素的定量分析[J].应用激光,2018,38(4):138-142.CUI Jin-long,MA Cui-hong,XU Shao-bin,et al.Quantitative analysis of Cr and Ni elements in LIBS molten steel based on free calibration method[J].Applied Laser,2018,38(4):138-142.
[16]
辛勇,李洋,蔡振荣,等.激光诱导击穿光谱液态金属成分在线分析仪在线监测熔融铝液中元素成分[J].冶金分析,2019,39(1):15-20.XIN Yong,LI Yang,CAI Zhen-rong,et al.On-line monitoring of element composition in molten aluminum by laser-induced breakdown spectroscopy online analyzer for liquid metal composition[J].Metallurgical Analysis,2019,39(1):15-20.
Lorenzetti G,Legnaioli S,Grifoni E,et al.Laser-based continuous monitoring and resolution of steel grades in sequence casting machines[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2015,112:1-5.
[19]
Delgado T,Ruiz J,Cabalín L M,et al.Distinction strategies based on discriminant function analysis for particular steel grades at elevated temperature using stand-off LIBS[J].Journal of Analytical Atomic Spectrometry,2016,31(11):2242-2252.
[20]
Ruiz J,Delgado T,Cabalín L M,et al.At-line monitoring of continuous casting sequences of steel using discriminant function analysis and dual-pulse laser-induced breakdown spectroscopy[J].Journal of Analytical Atomic Spectrometry,2017,32(6):1119-1128.
[21]
Cabalín L M,Delgado T,Ruiz J,et al.Stand-off laser-induced breakdown spectroscopy for steel-grade intermix detection in sequence casting operations.At-line monitoring of temporal evolution versus predicted mathematical model[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2018,146:93-100.
[22]
Meinhardta C,Sturmb V,Fleige R,et al.Laser-induced breakdown spectroscopy of scaled steel samples taken from continuous casting blooms[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2016,123:171-178.
[23]
Zeng Q,Pan C,Li C,et al.Online monitoring of corrosion behavior in molten metal using laser-induced breakdown spectroscopy[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2018,142:68-73.
[24]
Sturm V,Fleige R,Kanter M D,et al.Laser-induced breakdown spectroscopy for 24/7 automatic liquid slag analysis at a steel works[J].Analytical Chemistry,2014,86(19):9687-9692.
[25]
Zhang T,Wu S,Dong J,et al.Quantitative and classification analysis of slag samples by laser induced breakdown spectroscopy (LIBS) coupled with support vector machine (SVM) and partial least square (PLS) methods[J].Journal of Analytical Atomic Spectrometry,2015,30:368-374.
[26]
Bhatt C R,Goueguel C L,Jain J C,et al.Analysis of charcoal blast furnace slags by laser-induced breakdown spectroscopy[J].Applied Optic,2017,56(28):7789-7795.
[27]
Ahamer C M,Eschlböck-Fuchs S,Kolmhofer P J,et al.Laser-induced breakdown spectroscopy of major and minor oxides in steel slags:influence of detection geometry and signal normalization[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2016,122:157-164.
[28]
Li X,Yang J,Chang F,et al.LIBS quantitative analysis for vanadium slags based on selective ensemble learning[J].Journal of Analytical Atomic Spectrometry,2019,34(6):1135-1144.
[29]
Merk S,Scholz C,Florek S,et al.Increased identification rate of scrap metal using laser induced breakdown spectroscopy echelle spectra[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2015,112:10-15.
[30]
Aquino F W B,Santos J M,Carvalho R R V,et al.Obtaining information about valuable metals in computer and mobile phone scraps using laser-induced breakdown spectroscopy (LIBS)[J].RSC Advance,2015,5(82):67001-67010.
[31]
Castro J P,Pereira-Filho E R.Twelve different types of data normalization for the proposition of classification,univariate and multivariate regression models for the direct analyses of alloys by laser-induced breakdown spectroscopy (LIBS)[J].Journal of Analysis Atomic Spectrometry,2016,31(10):2005-2014.
[32]
Vors E,Tchepidjian K,Sirven J B.Evaluation and optimization of the robustness of a multivariate analysis methodology for identification of alloys by laser induced breakdown spectroscopy[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2016,117:16-22.
[33]
Campanella B,Grifoni E,Legnaioli S,et al.Classification of wrought aluminum alloys by ANN evaluation of LIBS spectra from aluminum scrap samples[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2017,134:52-57.
[34]
Shin S,Moon Y,Lee J,et al.Signal processing for real-time identification of similar metals by laser-induced breakdown spectroscopy[J].Plasma Science and Technique,2019,21(3):88-95.
[35]
Zhang T,Xia D,Tang H,et al.Classification of steel samples by laser-induced breakdown spectroscopy and random forest[J].Chemometrics and Intelligent Laboratory Systems,2016,157:196-201.
[36]
潘立剑,陈蔚芳,崔榕芳,等.主成分分析结合极限学习机辅助激光诱导击穿光谱用于铝合金分类识别[J].冶金分析,2020,40(1):1-6.PAN Li-jian,CHEN Wei-fang,CUI Rong-fang,et al.Application of laser-induced breakdown spectroscopy assisted by principal component analysis combined with extreme learning machine in the classification of aluminum alloy[J].Metallurgical Analysis,2020,40(1):1-6.
[37]
Nagy T O,Pacher U,Pöhl H,et al.Atomic emission stratigraphy by laser-induced plasma spectroscopy:quantitative depth profiling of metal thin film systems[J].Applied Surface Science,2014,302:189-193.
[38]
Nagy T O,Pacher U,Giesriegl A,et al.Depth profiling of galvanoaluminium-nickel coatings on steel by UV- and VIS-LIBS[J]. Applied Surface Science,2017,418:508-516.
[39]
Pacher U,Dinu M,Nagy T O,et al.Multiple wavelength stratigraphy by laser-induced breakdown spectroscopy of Ni-Co alloy coatings on steel[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2018,146:36-40.
[40]
Imran M,Sun L Y,Liu P,et al.Depth profiling of tungsten coating layer on CuCrZr alloy using LIBS approach[J].Surface and Interface Analysis,2019,51:210-218.
[41]
Sun L X,Wang W Y,Guo M T,et al.Small-invasive determination of iron content in coating of galvanized steel sheets by laser-induced breakdown spectroscopy[J].Journal of Iron & Steel Research Institute,2019,26(10):1137-1146.
[42]
Lednev V N,Sdvizhenskii P A,Filippov M N,et al.Elemental profiling of laser cladded multilayer coatings by laser induced breakdown spectroscopy and energy dispersive X-ray spectroscopy[J].Applied Surface Science,2017,416:302-307.
