Abstract:The microstructure evolution of intermetallic phases (σ phase and χ phase) in hot rolled 316L stainless steel during solution process was studied by means of scanning electron microscope (SEM), X-ray diffractometer (XRD) and electron backscatter diffractometer (EBSD). Meanwhile,the high temperature laser confocal microscope was used to observe the whole in-situ re-dissolution of intermetallic phases. The optimal solution temperature was determined. The results indicated that the phase transition process of γ+σ+χ→γ+σ+χ+α/FeCr→γ+α/FeCr occurred during solution process. The re-dissolution of intermetallic phases started at 1033.1℃ and ended at 1149.5℃. The re-dissolution time lasted for 21 seconds, and the optimum solution temperature for eliminating intermetallic phases was about 1150℃. Before the solution treatment, the morphology of banded structure distributed in the matrix was irregular, and the area percentages of χ phase and σ phase was 0.46% and 0.94%, respectively. After the solution treatment, the morphology of banded structure was uniform and mainly distributed in the form of ferrite and FeCr phase, while χ phase and σ phase were not observed.
Perron A,Toffolon-Masclet C,Ledoux X,et al.Understanding sigma-phase precipitation in a stabilized austenitic stainless steel (316Nb) through complementary CALPHAD-based and experimental investigations[J].Acta Materialia,2014,79:16-29.
[8]
Kuroda T.Role of sigma phase on hydrogen embrittlement of super duplex stainless steels[J].Transactions of JWRI:Transactions of Japan Welding Research Institute,2005,34(2):63-68.
[9]
陈嘉砚,杨卓越,杨武,等.双相不锈钢中σ相的形成特点及其对性能的影响[J].钢铁研究学报,2006,18(8):1-4.CHEN Jia-yan,YANG Zhuo-yue,YANG Wu,et al.Characteristic of phase σ precipitation and its effects on behavior in duplex stainless steel[J].Journal of Iron and Steel Research,2006,18(8):1-4.
[10]
Juuti T,Rovatti L,Porter D,et al.Factors controlling ambient and high temperature yield strength of ferritic stainless steel susceptible to intermetallic phase formation[J].Materials Science and Engineering:A,2018,726:45-55.
[11]
Barrilao J L,Kuhn B,Wessel E.Microstructure evolution and dislocation behaviour in high chromium,fully ferritic steels strengthened by intermetallic Laves phases[J].Micron,2018,108:11-18.
[12]
Bleck W,Song W W,Zimmermann A.Intermetallic phases in new steels[J].Materials Science Forum,2016,879: 9-14.
[13]
Melo E A,Magnabosco R.Influence of the heterogeneous nucleation sites on the kinetics of intermetallic phase formation in aged duplex stainless steel[J].Metallurgical and Materials Transactions A,2017,48(11):5273-5284.