1. Shougang Research Institute of Technology, Beijing 100043, China; 2. Beijing Key Laboratory of Green Recyclable Process for Iron & Steel Production Technology, Beijing 100043, China
Abstract：The influence study of sulfidation corrosion time of tinplate on the composition in corrosion products could promote the understanding of sulfidation corrosion mechanism of tinplate and the resolution for the problem of sulfur blackening. The immersion time of tinplate in sodium sulfide-acetic acid simulated solution (pH 6) was varied in experiments. The mass fraction of main elements as well as the component and valence state of S in products obtained with different sulfidation corrosion times was analyzed by X-ray photoelectron spectrometer (XPS). The results indicated that when the sulfidation corrosion time was prolonged from 2d and 9d to 23d, the mass fraction of S gradually increased, while the mass fraction of O firstly decreased and then increased. In finally stable sulfidation corrosion products, the mass fraction of Sn was near 0, and the mass fraction of Fe was fluctuated around 60%. Sn metal could only provide physical protection role on matrix. The components of S in sulfidation corrosion products mainly included S, S- and S2-, and had no change. However, the relative content of components in each valence state changed, i.e., the mass fraction of low-valence S decreased and the mass fraction of high-valence S increased. In other words, the combination state of S showed the trend of being oxidized in sulfidation corrosion process. The increase of Sn layer thickness and uniformity as well as the addition of reducing substances in canned matter were effective routes to reduce the sulfidation corrosion.
许斐范,生海,石云光,杨建炜. 硫蚀时间对镀锡板腐蚀产物成分的影响研究[J]. 冶金分析, 2018, 38(6): 7-11.
XU Fei-fan,SHENG Hai,SHI Yun-guang,YANG Jian-wei. The influence study of sulfidation corrosion time on the composition of tinplate corrosion products. , 2018, 38(6): 7-11.
曹曙,周焕勤,胡维健.电镀锡钢板生产工艺技术及其新发展[J].上海金属,1994,16(3):1-6.CAO Shu,ZHOU Huan-qin,HU Wei-jian.Process and technology and progress of electrolytic tinplate production[J].Shanghai Metals,1994,16(3):1-6.
[2]
黎敏,鞠新华,杨志强.镀锡板的电化学剥离及其耐蚀性研究[J].冶金分析,2016,36(11):17-23.LI Min,JU Xin-hua,YANG Zhi-qiang.Electrochemical stripping of tinplate and analysis of corrosion resistance property[J].Metallurgical Analysis,2016,36(11):17-23.
[3]
黄久贵,李宁,蒋丽敏,等.镀锡板耐蚀性研究及进展[J].电镀与环保,2003,23(6):5-9.HUANG Jiu-gui,LI Ning,JIANG Li-min,et al.Research and progess in the corrosion resistance of tinplate and its progess[J].Electroplating & Pollution Control,2003,23(6):5-9.
[4]
Barilli F,Fragni R,Gelati S,et al.Study of different types of lacquers used in food packing[J].Progress in Organic Coatings,2003,46:91-96.
[5]
Blunden S,Wallace T.Tin in canned food:a review and understanding of occurrence and effect[J].Food and Chemical Toxicology,2003,41:1651-1662.
[6]
Arenas M A,Conde A,Damborenea J J.Cerium:a suitable green corrosion inhibitor for Tinplate[J].Corrosion Science,2002,44(3):511-520.
[7]
王国勇,顾洪法.午餐肉罐头硫化黑变与容器材料选择的探讨[J].食品与发酵工业,2001,27(11):45-48.WANG Guo-yong,GU Hong-fa.The sulfide black in pork lunchern meat can and the selection of the material for container[J].Food and Fermentation Industries,2001,27(11):45-48.
[8]
刘世宏,王当憨,潘承璜.X射线光电子能谱分析[M].北京:科学出版社,1988.
[9]
Arenas M A,Garcia I,De Damborenea J.X-ray photoelectron spectroscopy study of the corrosion behavior of galvanized steel implanted with rare earths[J].Corrosion Science,2004,46(4):1033-1049.
[10]
Hanawa T,Hiromoto S,Yamamoto A,et al.XPS characterization of the surface oxide film of 316L stainless steel samples that were located in quasi-biological environments[J].Materials Transactions,2002,43(12):3088-3092.
[11]
Mora N,Cano E,Polo J,et al.Corrosion protection properties of cerium layers formed on tinplate[J].Corrosion Science,2004,46:563-578.
[12]
Long Z L,Zhou Y C,Xiao L.Characterization of black chromate conversion coating on the electrodeposited zinc-iron alloy[J].Applied Surface Science,2003,218:123-136.
[13]
Wagner C D,Riggs W M,Davis L E,et al.Handbook of X-ray photoelectron spectroscopy[M].Perkin-Elmer Corporation Physical Electronics Division,USA,1979.
