Abstract：For the analysis of complicated composition in stainless steel slag, the sample was prepared by fusion method under the following conditions: Li2B4O7-LiBO2 (m∶m=67∶33) was used as mixed flux, NH4NO3 was used as oxidizing agent, and LiBr solution (500g/L) was used as releasing agent. The extended fundamental parameter method in X-ray fluorescence spectrometry (XRF) analysis software UniQuant was adopted to establish and correct the background shape and impurity factor of stainless steel slag. The spectral interference and matrix effect were corrected using the spectral sensitivity coefficient and spectral overlapping coefficient. More than 20 components which possibly existed in stainless steel slag were analyzed. The quantitative analysis of 14 components (including CaO, MgO, SiO2, Al2O3, TiO2, MnO, Fe2O3, P2O5, SO3, F, Cr2O3, NiO, V2O5 and BaO) as well as qualitative and semi-quantitative analysis of other components in stainless steel slag were realized. The precision of sample preparation method was investigated, and the relative standard deviations (RSD, n=11) of determination results were between 0.15% and 11%. The precision test of standard sample JKS11 was conducted, and the RSD (n=11) were between 0.030% and 12%. The standard sample and actual sample of stainless steel slag were analyzed according to the experimental method. The found results of 14 main components were consistent with the certified values or those obtained by wet method.
阚斌,程坚平,宋祖峰.X荧光光谱法分析LF-VD精炼炉炉渣[J].光谱学与光谱分析,2004,24(10):1273-1275.KAN Bin,CHENG Jian-ping,SONG Zu-feng.Determination of LF-VD refining furnace slag by X ray fluorescence spectrometry[J].Spectroscopy and Spectral Analysis,2004,24(10):1273-1275.
[2]
童晓民,赵宏风,黄春燕,等.X-射线荧光光谱法测定炉渣中13种组分[J].冶金分析,2005,25(6):12-16.TONG Xiao-min,ZHAO Hong-feng,HUANG Chun-yan,et al.Determination of 13 components in slag by X-ray fluorescence spectrometry[J].Metallurgical Analysis,2005,25(6):12-16.
[3]
张殿英,李超,钱菁.X射线荧光光谱法测定转炉渣中8种成分[J].冶金分析,2009,29(6):41-46.ZHANG Dian-ying,LI Chao,QIAN Jing.Determination of eight components in converter slag by X-ray fluorescence spectrometry[J].Metallurgical Analysis,2009,29(6):41-46.
[4]
武映梅,罗惠君,林丽芳,等.X射线荧光光谱法测定冶金炉渣样中9种组分[J].冶金分析,2010,30(8):7-11.WU Ying-mei,LUO Hui-jun,LIN Li-fang,et al.Determination of nine components in metallurgical slag by X-ray fluorescence spectrometry[J].Metallurgical Analysis,2010,30(8):7-11.
[5]
唐梦奇,刘顺琼,袁焕明,等.粉末压片制样－波长色散X射线荧光光谱法测定进口铜矿石中的氟[J].岩矿测试,2013,32(2):254-257.TANG Meng-qi,LIU Shun-qiong,YUAN Huan-ming,et al.Determination of fluorine in import copper ores by wavelength dispersive X-ray fluorescence spectrometry with pressed powder preparation[J].Rock and Mineral Analysis,2013,32(2):254-257.
[6]
张祥,陆晓明,金德龙,等.熔融制样-X射线荧光光谱测定不锈钢渣中10种组分[J].冶金分析,2016,36(1):40-44.ZHANG Xiang,LU Xiao-ming,JIN De-long,et al.Determination of ten components in stainless steel slag by X-ray fluorescence spectrometry[J].Metallurgical Analysis,2016,36(1):40-44.
[7]
KATAOKA Yoshiyukki,FURUSAWA Eiichi1,KOHNO Hisayuki,等.基本参数法X-射线荧光光谱同时分析镍、钴和铁基合金[J].冶金分析,2009,29(5):6-11.KATAOKA Yoshiyukki,FURUSAWA Eiichi1,KOHNO Hisayuki,et al.Simultaneous analysis of nickel,cobalt and iron base alloys using X-ray fluorescence spectrometry with the fundamental parameter method[J].Metallurgical Analysis,2009,29(5):6-11.
[8]
吉昂,陶光仪,卓尚军,等.X射线荧光光谱法分析[M].北京:科学出版社,2003.
[9]
UniQuant Integrated Programme for OXSAS Software[M].Thermo Fisher Scientific-KJu.
