Study on distribution analysis method in crack zone of pipeline steel by laser ablation-inductively coupled plasma mass spectrometry
YANG Li-xia1, CHEN Jian2, SONG Quan-wei3,4, LI Dong-ling1, JIA Shu-jun2, LI Xiao-jia*1
1.Beijing Key Laboratory of Metal Material Characterization,Central Iron and Steel Research Institute,Beijing 100081,China; 2.Institute for Engineering Steel,Central Iron and Steel Research Institute,Beijing 100081,China; 3.State Key Laboratory of Petroleum Pollution Control,Beijing 102206,China; 4.CNPC Research Institute of Safety and Environmental Technology,Beijing 102206,China
Abstract：It is significant that distribution micro-analysis technique based on laser ablation-inductively coupled plasma mass spectrometry will contribute to the hydrogen induced cracking mechanism. Both the working parameters of laser ablation (LA), including carrier gas flow, ablation spot sizes, ablation rates, and the working parameters of ICP-MS, such as carrier gas flow and integral dwell time of isotopes, are optimized. After the matrix 57Fe is used as the internal standard,the calibration curve are obtained by the line scanning ablation of GSBH40068-X-93 standard samples. Then, the quantitative analysis method of Al, Mn, Ni, Cu and Mo in pipeline steel by LA-ICP-MS is established, which is successfully applied to component distribution analysis for the crack zone of X80 pipeline steel. The quantitative analysis results of LA-ICP-MS can match the found values of inductively coupled plasma atomic emission spectrometry(ICP-AES), the two-dimensional distribution of the elements in the crack zone are basically consistent with line analysis results by electron probe X-ray micro-analysis (EPMA), which demonstrate that the proposed method for distribution analysis in pipeline steel samples by LA-ICP-MS is of accuracy and effectiveness. In addition, the two-dimensional distribution graphs of the elements can reflect the segregation of elements, which further reveals that the formation of cracks in samples may be related to the the presence of Al2O3, MnS inclusions, and carbon-rich phase as well as the segregation of Mo. Accordingly, the proposed method will provide an efficient kind of analysis and quality control measurement for the hydrogen induced cracking mechanism and the development of new materials.
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YANG Li-xia, CHEN Jian, SONG Quan-wei, LI Dong-ling, JIA Shu-jun, LI Xiao-jia. Study on distribution analysis method in crack zone of pipeline steel by laser ablation-inductively coupled plasma mass spectrometry. , 2017, 37(4): 1-9.
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