Abstract：The sample was dissolved using 2.0 mL of nitric acid and 10.0 mL of hydrochloric acid.As 188.979 nm, Sn 189.927 nm and Sb 206.836 nm were selected as the analysis lines.The background was deducted by two-point correction method.The analysis method of arsenic, tin and antimony in steel for ship by inductively coupled plasma atomic emission spectrometry (ICP-AES) was established.The standard solution series were prepared by matrix matching method for the plotting of calibration curve.The linearity of calibration curve for each element was good with correlation coefficient higher than 0.999. The detection limits were less than0.000 2% (mass fraction). The content of arsenic, tin and antimony in standard sample of low alloy steel was determined according to experimental method. The relative standard deviations (RSD, n=10) were between 0.38% and 1.9%. The determination results were consistent with the certified values. The proposed method was also applied to the determination of arsenic, tin and antimony in steel sample for ship. RSD (n=10) was less than 5% and the found results were consistent with those obtained by hydride generation-atomic fluorescence spectrometry.
杜米芳,聂富强,杜丽丽,刘攀. 电感耦合等离子体原子发射光谱法测定船用钢中砷锡锑[J]. 冶金分析, 2017, 32(2): 70-75.
DU Mi-fang,NIE Fu-qiang,DU Li-li,LIU Pan. Determination of arsenic,tin and antimony in steel for ship by inductively coupled plasma atomic emission spectrometry. , 2017, 32(2): 70-75.
武映梅,宋兆华,萧民强. X射线荧光光谱法测定低合金钢中的12个元素[J].南方金属,2005(1):27-29,31.WU Ying-mei,SONG Zhao-hua,XIAO Min-qiang.Elemental determination in low-alloy steels by X-Ray fluorescence spectrometry[J].Southern Metals,2005(1):27-29,31.
[2]
王明军,何雪梅,焦万里,等. 微波消解-电感藕合等离子体质谱法测定钢铁中砷、铅、锑、锡、铜[J].化工矿产地质,2011,33(1):58-60.WANG Ming-jun,HE Xue-mei,JIAO Wan-Li,et al. The determination of arsenic,lead,antimony,tin and copperin steel and iron by microwave digestion-inductively coupled plasma mass spectrometry[J].Chemical Industry Mineral Prouducts and Geology,2011,33(1):58-60.
[3]
马尚.利用电感耦合等离子体质谱仪分析技术联合测定合金中的锡、锑、磷[J].黑龙江科技信息,2013(3):78.MA Shang. The unitedetermination of tin,antimony,phosphorus in the alloy by inductively coupled plasma mass spectrometry[J].The Heilongjiang Science and Technology Information,2013(3):78.
[4]
郑善峰,吴长浩.应用发射光谱法测定钢中砷、锡、铅、锑、铋的含量[J].一重技术,2004(3):37-39.ZHENG Shan-feng,WU Chang-hao.The determination of content of arsenic,tin,lead,antimony and bismuth in steel by emission spectrometry[J]. CFHI Technology,2004(3):37-39.
[5]
陆伟星,朱伟长.ICP-AES法直接测定钢中铅、锡、砷、锑和铋[J].安徽工业大学学报:自然科学版,2009,26(4):386-389,393.LU Wei-xing,ZHU Wei-chang. The direct determination of lead,tin,arsenic,antimony and bismuth in steel by ICP-AES[J].Journal of Anhui University of Technology:Natural Science Edition,2009,26(4):386-389,393.
[6]
赵江林.ICP法测定钢中铅锡砷锑铋[J].商情,2013(25):258.
[7]
张伟东,周春丽,李建梅,等.氢化物发生-电感耦合等离子体原子发射光谱法测定钢中微量砷、锑、铋[J].理化检验:化学分册,2012,48(10):1161-1163. ZHANG Wei-dong,ZHOU Chun-li,LI Jian-mei,et al.HG-ICP-AES determination of trace amounts of arsenic,antimony and bismuth in steel[J]. Physical Testing and Chemical Analysis Part B:Chemical Analysis,2012,48(10):1161-1163.
[8]
支国瑞,刘吉红,马宏彦,等.ICP-AES法直接测定钢中微量砷、锡、锑[J].光谱实验室,2002,19(4):485-487.ZHI Guo-rui,LIU Ji-hong,MA Hong-yan,et al.The directly determination of trace arsenic,tin,antimony in steel by ICP-AES[J]. Spectroscopy Laboratory,2002,19(4):485-487.
[9]
刘金祥,李文彪.电感耦合等离子体原子发射光谱法同时测定低合金钢中常量及痕量元素[J].理化检验:化学分册,2008,44(增):91-94. LIU Jin-xiang,LI Wen-biao.Simultaneous determination of constant and trace elements in low alloy steel by ICP-AES[J]. Physical Testing and Chemical Analysis Part B:Chemical Analysis,2008,44(Suppl.):91-94.
[10]
韩华云,唐静,王哲光,等.氢化物发生-原子荧光光谱法测定钢中微量锡[J].冶金分析,2008,28(6):45-48.HAN Hua-yun,TANG Jing,WANG Zhe-guang,et a1.Determination of trace tin in steel by hydride generation atomic fluorescence spectrometry[J]. Metallurgical Analysis,2008,28(6):45-48.
