Abstract：Refined nickel is a high-quality raw material for stainless steel smelting. The refined nickel products include general nickel and nickel bean. The impurity elements should be detected. The sample was dissolved with nitric acid (1+1). Si 251.612 nm, Mn 257.610 nm, P 178.217 nm, Fe 259.940 nm, Cu 324.754 nm, Co 238.892 nm, Mg 279.553 nm, Al 396.153 nm, Zn 206.191 nm and Cr 267.716 nm were selected as analytical lines.The background interference was eliminated by off-peak background deduction correction method. The calibration curve was prepared by nickel-free matrix matching method. The content of 10 elements in refined nickel (including silicon, manganese, phosphorus, iron, copper, cobalt, magnesium, aluminum, zinc and chromium) was determined by inductively coupled plasma atomic emission spectrometry (ICP-AES). The linear correlation coefficients of calibration curves of elements were higher than 0.999 5. The detection limits of elements were between 0.000 12% and 0.001 9%. The content of silicon, manganese, phosphorus, iron, copper, cobalt, magnesium, aluminum, zinc and chromium in refined nickel sample and Nickel200 standard sample was determined according to the experimental method. The relative standard deviations (RSD, n=11) were between 1.0% and 10%. The found results of standard sample were consistent with the certified values. The recoveries for refined nickel samples were between 90% and 105%.
王金磊.电感耦合等离子体质谱法高纯镍粉中18种杂质元素含量的测定[J].四川化工,2013,15(6):33-35.WANG Jin-lei.Determination of eighteen impurity element in high-purity nickel powder by inductively coupled plasma mass spectrometry[J].Sichuan Chemical Industry,2013,15(6):33-35.
[2]
成勇.微波消解-电感耦合等离子体质谱法测定高纯镍板中痕量元素[J].冶金分析,2008,28(3):9-13.CHENG Yong.Determination of trace elements in high-purity nickel by inductively coupled plasma mass spectrometry with microwave digestion[J].Metallurgical Analysis,2008,28(3):9-13.
[3]
杨海岸,罗舜,闫豫昕,等. 辉光放电质谱法测定高纯镍中16种痕量杂质元素[J].冶金分析,2015,35(5):1-6.YANG Hai-an,LUO Shun,YAN Yu-xin,et al.Determination of sixteen trace impurity elements in high-purity nickel by glow discharge mass spectrometry[J].Metallurgical Analysis,2015,35(5):1-6.
[4]
张瑞霖,张为,戴学谦. ICP-AES法测定金属镍中杂质元素[J].冶金分析,2003,23(4):58-59.ZHANG Rui-lin,ZHANG Wei,DAI Xue-qian.Determination of impurities in nickel by ICP-AES[J].Metallurgical Analysis,2003,23(4):58-59.
[5]
周晨光,赵磊,刘明,等.电感耦合等离子体原子发射光谱法测定镍丝中的铁、锰、铜[J].天津化工,2015,29(1):50-51.ZHOU Chen-guang,ZHAO Lei,LIU Ming,et al.Determination of iron,manganese and copper element in nickel wire by inductively coupled plasma atomic emission spectrometry[J].Tianjin Chemical Industry,2015,29(1):50-51.
[6]
王凌,吴燕. ICP-AES测定电解镍中的杂质元素[J].光谱实验室,2013,30(3):1472-1475.WANG Ling,WU Yan.Determination of impurity element in electrolytic nickel by ICP-AES[J].Chinese Journal of Spectroscopy Laboratory,2013,30(3):1472-1475.
[7]
刘琰,夏阳,牟新玉. ICP-AES法测定高纯金属镍中杂质元素[J].安徽冶金,2005(3):16-17,34.LIU Yan,XIA Yang,MU Xin-yu.Determination of impurities element in high-purity nickel by ICP-AES[J].Anhui Metallurgical,2005(3):16-17,34.
[8]
李敏,龚琦,卢科,等.离子交换纤维柱分离-电感耦合等离子体原子发射光谱法测定金属镍及其化合物中铬[J].冶金分析,2015,35(10):8-13.LI Min,GONG Qi,LU Ke,et al.Determination of chromium in nickel and its compounds by inductively coupled plasma atomic emission spectrometry with anion exchange fiber column separation[J].Metallurgical Analysis,2015,35(10):8-13.
[9]
吴旻,陈莉,王巧利,等. ICP-AES法测定高纯金属镍中铁杂质元素[J].航空与航天,2009(1):15-16.WU Min,CHEN Li,WANG Qiao-li,et al.Determination of iron impurity element in high-purity nickel by ICP-AES[J].Aviation and Aerospace,2009(1):15-16.
[10]
郑国经.ICP-AES分析技术的发展及其在冶金分析中的应用[J].冶金分析,2001,21(1):36-43.ZHENG Guo-jing.Development of ICP-AES and its application in metallurgical analysis development of ICP-AES and its application in metallurgical analysis [J].Metallurgical Analysis,2001,21(1):36-43.
