Abstract：In order to ascertain the phase composition of zinc smelting slag, the X-ray diffraction (XRD) and energy dispersive spectrum (EDS) were adopted. The phase analysis results indicated that the phase composition of zinc smelting slag could be accurately determined by XRD and EDS which were associated with scanning electron microscope(SEM). That is,the X-ray powder diffraction patterns of multi-phase mixed smelting slag were compared and analyzed with the standard spectral lines of phases,and the content of elements was determined according to the micro area diffraction EDS of scanning electron microscope. It provided basis for the comprehensive utilization of smelting slag. Under the experimental conditions, it was found that the oxygen powder acid leaching residue sample of zinc smelting slag mainly included Pb, S, O and Zn. The main phases were PbSO4 and ZnS. The elements in copper-cadmium slag mainly included O, Zn, Al and Cd, and the main phases were ZnS and ZnSO4·6H2O. The cadmium existed in copper-cadmium reside in the form of CdS, CdSO4, CdO and Cd. The main elements in bag filter oxide powder were Zn, O, Pb and S, and the main phases were ZnO and ZnS.
韦岩松,吕雪丽,王振峰,等.锌铟冶炼过程镉砷的流向及在废渣中的分布[J].湿法冶金,2014,33(3):219-221.WEI Yan-song,L Xue-li,WANG Zhen-feng,et al.Flow direction and distribution in waste residue of cadmium and arsenic in zinc and indium smelting process[J].Hydrometallurgy of China,2014,33(3):219-221.
[2]
王海军.复杂矿石中金的化学物相分析进展[J].黄金科学技术,2013,21(2):55-60.WANG Hai-jun.Chemical phase analysis of gold in the complex gold ore and its development[J].Gold Science and Technology,2013,21(2):55-60.
[3]
Matthea A P, Marjorie A L.Comparison of nanoscaled and bulk NiO structural and environmental characteristics by XRD, XAFS and XPS[J].Chem.Mater.,2012,24:4483-4490.
[4]
田志宏,张秀华,田志广.X射线衍射技术在材料分析中的应用[J].工程与试验,2009,49(3):40-42.TIAN Zhi-hong,ZHANG Xiu-hua,TIAN Zhi-guang. Application of X-ray diffraction technology in material analysis[J].Engineering and Test,2009,49(3):40-42.
[5]
曾超,何维.赤泥物相的X射线粉末衍射Rietveld法定量分析研究[J].冶金分析,2014,34(8):1-6.ZENG Chao,HE Wei.Study on quantitative phase analyses of red mud by Rietveld method from X-ray powder diffraction[J].Metallurgical Analysis,2014,34(8):1-6.
[6]
丰芸,李寒旭,丁立明.利用XRD 分析高温下淮南煤灰矿物质变化[J].安徽建筑工业学院学报:自然科学版,2008,16(5):53-57.FENG Yun,LI Han-xu,DING Li-ming.Study of huainan coal ash mineral variation under high temperature with XRD[J].Journal of Anhui Institute of Architecture & Industry:Natural Science,2008,16(5):53-57.
[7]
徐玉林,徐明波,杨水金.XRD在无机合成中物相分析的应用[J].湖北师范学院学报:自然科学版,2013,33(4):40-46,62.XU Yu-lin,XU Ming-bo,YANG Shui-jin.Application of X-ray powder diffraction in phase analysis of inorganic synthesis[J].Journal of Hubei Noral University:Natural Science,2013,33(4):40-46,62.
[8]
Wang X Y,Guo G Q,Nie X W,et al.Cytochemical localization of cellulase activity in pollen mother cells of David lilyduring meiotic prophase I and its relation to secondary formation of plasmodesmata[J].Protoplasma,1998,204:128-138.
[9]
晋勇.X 射线衍射分析技术课程的实验教学研究[J].实验科学与技术,2014,12(6):172-174,186.JIN Yong.Study of X-ray diffraction analysis technology for experiment teaching[J].Experiment Science and Technology, 2014,12(6):172-174,186.
[10]
孙杰,安成强,谭勇,等.镀锡液锡泥中锡的物相分析[J].冶金分析,2012,32(10):56-59.SUN Jie,AN Cheng-qiang,TAN Yong,et al.Study of phase analysis on tin slurry in tin electroplating solution[J].Metallurgical Analysis,2012,32(10):56-59.
[11]
Remigijus J,Darius A,Putinas K,et al.XRD,SEM and photoelectrochemical characterization of ZnSe electrodepositedonCu and Cu-Sn substrates[J].Electrochimica Acta,2012,70:118-123.
[12]
李建欣,宋党育,张军营,等.X射线衍射数据分析系统评价[J].岩矿测试,2008,27(3):189-192,196.LI Jian-xin,SONG Dang-yu,ZHANG Jun-ying,et al.Evaluation of the X-ray diffraction data analysis system[J].Rock and Mineral Analysis,2008,27(3):189-192,196.
[13]
赫英利. 粉末X射线衍射鉴定一种重整催化剂的晶体物相[J].分析仪器,2015(3):23-25.HE Ying-li.Identification of crystalline phase in a reforming catalyst by powder X-ray diffraction[J].Analytical Instrumentation,2015(3):23-25.
[14]
任轶,吴继华.浸渣及烟尘中镉的物相分析[J].云南冶金,2002,31(2):63-65.REN Yi,WU Ji-hua.Chemical phase analysis of cadmium in sulfuric acid smoke and leach residue[J].Yunnan Metallurgy, 2002,31(2):63-65.
