Abstract：There was no test method for asbestos in oxide scale in China so far. In this paper, after the sample was dispersed with isopropanol and followed by suction filtration onto the glass fiber filter, a method was proposed for determination of chrysotile, crocidolite and amosite in oxide scale by X-ray diffraction absorption base standard correction method. The linearity of calibration curves for determination of chrysotile, crocidolite and amosite was good. The detection limit was 0.004 5%, 0.002 3% and 0.000 65%, and the lower limit of quantitation was 0.014%, 0.006 9% and 0.002 0%, respectively. The prepared oxide scale with 0.20% of asbestos was analyzed. The relative standard deviations (RSD, n=10) of determination results were all less than 8%. The proposed method was verified with the oxide scale sample. The determination results of asbestos were consistent with the reference values. The method could meet the detection requirements for trace asbestos in oxide scale with mass fraction of 0.10%-0.50%.
鲍俊,王全林.石棉控制法规及其检测方法[J]. 岩矿测试,2010,30(5):644-653. BAO Jun, WANG Quan-lin. Review of control laws and detection methods for asbestos[J].Rock and Mineral Analysis, 2010, 30(5): 644-653.
[2]
封亚辉,李建军,程薇,等.自行车闸皮中石棉的鉴定方法[J].硅酸盐通报,2009,28(5):1102-1106. FENG Ya-hui, LI Jian-jun, CHENG Wei, et al. Method for identifying asbestos in brake rubber of bicyle[J]. Bulletin of the Chinese Ceramic Society, 2009, 28(5): 1102-1106.
[3]
封亚辉,程薇,张梅,等.爽身粉中石棉鉴定方法的研究[J].地质学刊,2009,33(4):417-419. FENG Ya-hui, CHENG Wei, ZHANG Mei, et al. Study on determination method of asbestos in toilet powder[J]. Journal of Geology, 2009, 33(4): 417-419.
[4]
陈永康,李德辉.化妆品中石棉检测方法的研究[J].化学工程师,2010(9):22-25. CHEN Yong-kang, LI De-hui. Research of testing method for asbestos in cosmetic[J].Chemical Engineer, 2010(9): 22-25.
[5]
薛雍,江向峰,钟玉锋.标准曲线法X射线粉晶衍射直接分析滑石中微量石棉[J].岩矿测试,2010,29(3):322-324. XUE Yong, JIANG Xiang-feng, ZHONG Yu-feng. Quantitative determination of trace asbestos in talcum by X-ray powder diffraction with external standardization[J].Rock and Mineral Analysis,2010,29(3):322-324.
[6]
张梅,高孝礼,黄光明,等.微量石棉的X射线衍射定量检测[J].岩矿测试,2010,29(3):309-312. ZHANG Mei, GAO Xiao-li, HUANG Guang-ming, et al.Quantitative detection of trace asbestos by X-ray diffraction system[J]. Rock and Mineral Analysis, 2010, 29(3): 309-312.
[7]
胡晓静,赵景红,钟志光,等. X射线衍射分段扫描法鉴别滑石粉中微量石棉[J].冶金分析,2011,31(7):35-39. HU Xiao-jing, ZHAO Jing-hong, ZHONG Zhi-guang, et al. Identification of micro asbestos in talc powder by a three-step scanning method using X-ray diffraction spectrometry[J]. Metallurgical Analysis, 2011, 31(7): 35-39.
[8]
李艳华,高骏,鲍俊,等. 密封垫片中石棉的检测方法研究[J].中国测试,2011,37(5):47-49. LI Yan-hua, GAO Jun, BAO Jun, et al. Study on testing asbestos in gasket[J].China Measurement and Test, 2011, 37(5): 47-49.
[9]
何乔桑,邓元,彭静,等. 粉状化妆品中石棉的检测方法[J].化工时刊,2011,25(9):25-27. HE Qiao-sang, DENG Yuan, PENG Jing. Determination of asbestos in powder cosmetics[J].Chemical Industry Times, 2011, 25(9): 25-27.
