Review of the research on the determination of trace iron with spectrophotometry
LI Guo-qiang1, 2, YANG Jian-jun2, HE Jia-hong1, 2, SONG Zhong-rong2, XU Qiang*2
1. Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China;2. College of Materials and Chemical Engineering, Chongqing University of Arts and Sciences, Chongqing 402160, China
Abstract：A review on the progress in recent years (2000-2012) of the spectrophotometric method for the determination of trace iron was presented. The content concerned the direct significant (faded) color spectrohotometry, catalytic kinetic spectrophotometry, inhibitory kinetic spectrophotometry, fluorospectrometry, chemical luminescence analysis and coupling techniques. The reaction medium, detection limit, linear range and the practical application object of different analytical methods are summarized and outlined. In order to improve the determination of iron by spectrophotometry, the proposal including the enhancement of the instruments’ capabilities to increase the sensitivity and reduce the determination error; the development of highly sensitive, selective, stable and environmental-friendly coloration reagents to improve the detection methods; and the combination with highly effective separation and enrichment detection techniques to reduce the interference and improve the systematic accuracy was proposed.
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