Abstract：The researches on determination method of tetraethyl lead in environmental water since 1990s were reviewed. The sample preparation methods and detection technologies were commented. Thereinto, purge and trap-gas chromatography/mass spectrometry (PT-GC/MS) had many advantages including fully automatic pretreatment of sample, high sensitivity, exempt from organic extraction reagent, highly efficient separation, qualitative and quantitative analysis, so it was worth popularizing in the monitoring of tetraethyl lead in environmental water. It was reported in some references that, there was the suspected “poisoning” phenomenon for trap or mass spectrometry detector during the determination of tetraethyl lead in environmental water by PT-GC/MS, which may be caused by the poor short-term stability of tetraethyl lead in water sample, and the key influencing factors on its stability and solutions should be further studied.
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