Abstract： The basic condition of the reference on the analysis of phosphate ores at home and abroad was commented. An review was conducted on the literature of the simultaneous analysis of multi-elements in phosphate ore and its main technology and methods (the characteristics, detection capability, precision and accuracy of X-ray fluorescence spectroscopy and inductively coupled plasma atomic emission spectrometry/mass spectrometry technology), and the research progress and application prospect of phosphate ore analysis technology. The result indicated that X-ray fluorescence spectrometry and inductively coupled plasma atomic emission spectrometry/mass spectrometry technology was the most effective method for the multi-element analysis of phosphate ore. The former method was mainly used for the determination of major and minor components while the latter one was featured with trace component analysis. Finally, according to the current situation of domestic phosphate ore analysis, the future progress of domestic phosphate analysis technology and the related suggestions were discussed and proposed.
［12］ 王毅民,王晓红,高玉淑. 地球科学中的现代分析技术［J］. 地球科学进展(Advances in Earth Science), 2003, 18(3): 476-482.
［13］ 邓赛文,王祎亚,王毅民.中国磷矿石分析文献评介［J］. 岩矿测试(Rock and Mineral Analysis), 2011, 30(3): 384-390.
［14］ Brenner I B, Watson A E, Russell G M, et al. A new approach to the determination of the major and minor constituents in silicate and phosphate rocks［J］. Chemical Geology, 1980, 28: 321-330.
［15］ Issahary D, Pelly I. Simultaneous multielement analysis of phosphates by X-Ray fluorescence［J］. X-Ray Spectrometry, 1982, 11(1): 8-12.
［16］ Shenberg C, Nir-el Y, Alfassi Z, et al. Rapid and simultaneous determination of U,F,A1,Ca and V in phosphate rocks by a combination of delayed neutron and γ-ray spectrometry techniques［J］. Journal of Radioanalytical and Nuclear Chemistry, 1987, 114(2): 367-377.
［17］ AI-Merey R, Bowen H J M. Determination of the rare-earth elements in phosphate rocks using both inductively coupled plasma atomic emission spectrometry and instrumental neutron activation analysis［J］. J.Radioanal. Nucl. Chem. Letters, 1991, 153(3): 221-234.
［18］ Bahattin G, Candan H A. Determination of some rare elements in phosphate rocks by inductively coupled plasma atomic emission spectrometry［J］. Spectroscopy Letters, 1991, 24(9): 1229-1236.
［19］ Eid M A, Broekaert J A C, Tschpel P. Application of ICP-AES to the determination of rare earth elements in phosphate samples［J］. Fresenius J Anal. Chem., 1992, 342: 107-112.
［20］ Hassan A M, Madani J, Aboulmomen M, et al. Neutron activation of saudi hematite and phosphate samples using the 241Am-Be Neutron Irradiation Facility［J］. JKAU:Sci., 1994, 6: 105-122.
［21］ Hayumbu P, Haselberger N, Markowicz A, et al. Analysis of rock phosphates by X-Ray fluorescence spectrometry［J］. Appl. Radiat. Isot., 1995, 46(10): 1003-1005.
［22］ Addas Y A J, AbduFattah A R F, Mamoon A. XRF assay of uranium and other elements in phosphate ores［C］.The Fourth Saudi Engineering Conference. Jeddah-Saudi Arabia: The Faculty of Engineering King Abdulaziz University, 1995,5: 319-322.
［23］ Eissa E A, Rofail N B, Ali R A, et al. Investigation of an Egyptian phosphate ore sample by neutron activation analysis technique［J］. Radiat Phys. Chem., 1996, 47(5): 705-708.
［24］ Rosenwasser S, Asimellis G, Bromley B, et al. Development of a method for automated quantitative analysis of ores using LIBS［J］. Spectrochimica Acta: Part B, 2001, 56: 707-714.
［25］ Safi M J, Rao M B, Rao K S P, et al. Chemical analysis of phosphate rock using different methods -advantages and disadvantages［J］. X-Ray Spectrometry, 2006, 35: 154-158.
［26］ Adam A A, Eltayeb M A H. Uranium abundance in some sudanese phosphate ores［J］. The Journal of the Argentine Chemical Society, 2009, 97(2): 166-177.
［27］ Fajber R, Simandl G J. Evaluation of rare earth element-enriched sedimentary phosphate deposits using portable X-ray fluorescence (XRF) instruments［J］. Geological Fieldwork, 2012,1: 199-210.
［40］ 李东,赵军. ICP-AES法测定磷矿石中主量、痕量成分［J］. 光谱学与光谱分析(Spectroscopy and Spectral Analysis), 2001, 21(2): 233-234.
［41］ Wang Xiao-hong, Li Guo-hui, Zhang Qin, et al. Determination of major, minor and trace elements in seamount phosphorite by XRF［J］. Geostandards and Geoanalytical Research, 2004, 28(1): 81-88.
［50］ 王和平,王海良,赵志全. 《磷矿石和磷精矿化学分析方法》国家标准修订说明［J］. 化工标准化与质量监督(Chemical Standard and Quality Supervision), 1996, 8: 8-9.
［51］ Govindaraju K. 1994 compilation of working values and samples description for 383 geostandards［J］. Geostandards Newsletter, 1994, 18 (Special Issue): 158.
