Research progress of solid phase extraction adsorbent
HUANG Yun-rui1, ZHOU Qing-xiang2
1. College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China; 2. College of Geosciences, China University of Petroleum Beijing, Beijing 102249, China
Abstract: The research progress of solid phase extraction adsorbent was reviewed in this paper. The application process of several common adsorbents in the analysis of environmental samples was mainly introduced, including activated carbon, organic polymer resin, bonded silica gels, nanometer materials and molecularly imprinted adsorbent, and the advantages, disadvantages and application scope of each adsorbent were analyzed. Meanwhile, the development trend and prospect of solid-phase extraction adsorbents were proposed. The researches in future should be focused on the development of adsorbents with large specific surface area, strong adsorptive capacity, easy to elution and good selectivity.
[5] Pichon V. Solid-phase extraction for multiresidue analysis of organic contaminants in water[J]. Journal of Chromatography A, 2000, 885: 195-215.
[6] Prosen H, Kralj L. Solid-phase microextraction[J]. Trends Analytical Chemistry, 1999, 18: 272-282.
[7] Vuckovic D, Zhang X, Cudjoe E, et al. Solid-phase microextraction in bioanalysis: New devices and directions[J]. Journal of Chromatography A, 2010, 1217: 4041-4060.
[8] Tsai W C, Huang S D. Dispersive liquid-liquid microextraction with little solvent consumption combined with gas chromatography-mass spectrometry for the pretreatment of organochlorine pesticides in aqueous samples[J]. Journal of Chromatography A, 2009, 1216: 5171-5175.
[9] Cortada C, Vidal L, Pastor R, et al. Determination of organochlorine pesticides in water samples by dispersive liquid-liquid microextraction coupled to gas chromatography-mass spectrometry[J]. Analytica Chimica Acta, 2009, 649: 218-221.
[10] Punincrespo M, Lageyusty M. Comparison of supercritical fluid extraction and Soxhlet extraction for the determination of PCBs in seaweed samples[J]. Chemosphere, 2005, 59: 1407-1413.
[11] Lambropoulou D, Konstantinou I, Albanis T. Sample pretreatment method for the determination of polychlorinated biphenyls in bird livers using ultrasonic extraction followed by headspace solid-phase microextraction and gas chromatography-mass spectrometry[J]. Journal of Chromatography A, 2006, 1124: 97-105.
[12] Braus H, Middleton F M, Walton G. Organic chemical compounds in raw and filtered surface waters[J]. Analytical Chemistry, 1951, 23: 1160-1164.
[13] Fu C G, Xu H D. High-performance liquid chromatography with post-column chemiluminescence detection for simultaneous determination of trace N-nitrosamines and corresponding secondary amines in groundwater[J]. The Analyst, 1995, 120: 1147-1151.
[15] Sojo L E, Djauhari J. Determination of chlorophenolics in waters by membrane solid-phase extraction: comparison between C and activated carbon 18 membranes and between modes of extraction and elution[J]. Journal of Chromatography A, 1999, 840: 21-30.
[16] Ensafi A A, Shiraz A Z. On-line separation and preconcentration of lead(II) by solid-phase extraction using activated carbon loaded with xylenol orange and its determination by flame atomic absorption spectrometry[J]. Journal of Hazardous Materials, 2008, 150: 554-559.
[17] Starvin A M, Rao T P. Solid phase extractive preconcentration of uranium(VI) onto diarylazobisphenol modified activated carbon[J]. Talanta, 2004, 63: 225-232.
[18] Riley J P, Taylor D. The analytical concentration of traces of dissolved organic materials from sea water with Amberlite XAD-1 resin [J]. Analytica Chimica Acta, 1969, 46: 307-309.
[19] Burnham A K, Calder G V, Fritz J S, et al. Identification and estimation of neutral organic contaminants in potable water [J]. Analytical Chemistry, 1972, 44: 139-142.
[20] Weigel S, Bester K, Huhnerfuss H. New method for rapid solid-phase extraction of large-volume water samples and its application to non-target screening of North Sea water for organic contaminants by gas chromatography-mass spectrometry[J]. Journal of Chromatography A, 2001, 912: 151-161.
[21] Bratkowska D, Fontanals N, Borrull F, et al. Hydrophilic hypercrosslinked polymeric sorbents for the solid-phase extraction of polar contaminants from water[J]. Journal of Chromatography A, 2010, 1217: 3238-3243.
[22] May W E, Chesler S N, Cram S P, et al. Chromatographic analysis of hydrocarbons in marine sediments and seawater[J]. Journal of Chromatography Science, 1975, 13: 535-540.
[23] Little J N, Fallick G J. New considerations in detector-application relationships[J]. Journal of Chromatography, 1975, 112: 389-397.
[24] Zamperlini G C M, Santiago-Silva M,Vilegas W. Solid-phase extraction of sugar cane soot extract for analysis by gas chromatography with flame ionisation and mass spectrometric detection[J]. Journal of Chromatography A, 2000, 889: 281-286.
[25] Otero R R, Grande B C,Gandara J S. Multiresidue method for fourteen fungicides in white grapes by liquid-liquid and solid-phase extraction followed by liquid chromatography-diode array detection[J]. Journal of Chromatography A, 2003, 992: 121-131.
[26] Delcarlo M, Pepe A, Sacchetti G, et al. Determination of phthalate esters in wine using solid-phase extraction and gas chromatography–mass spectrometry[J]. Food Chemisyry, 2008, 111: 771-777.
[27] Fan Y, Feng Y Q, Da S L. On-line selective solid-phase extraction of 4-nitrophenol with beta-cyclodextrin bonded silica[J]. Analytica Chimica Acta, 2003, 484: 145-153.
[29] 薛群基, 徐康. 纳米化学[J]. 化学进展(Progress in Chemistry), 2000, 12(4): 431-444.
[30] Iijima S. Helical microtubules of graphitic carbon[J]. Nature, 1991, 354: 56-58.
[31] Cai Y, Jiang G, Liu J, et al. Multiwalled carbon nanotubes as a solid-phase extraction adsorbent for the determination of bisphenol A, 4-n-nonylphenol, and 4-tert-octylphenol[J]. Analytical Chemistry, 2003, 75: 2517-2521.
[32] Zhou Q, Wang W, Xiao J, et al. Comparison of the enrichment efficiency of multiwalled carbon Nanotubes, C18 silica, and activated carbon as the adsorbents for the solid phase extraction of atrazine and simazine in water samples[J]. Microchimica Acta, 2005, 152: 215-224.
[33] Zhou Q, Ding Y, Xiao J. Sensitive determination of thiamethoxam, imidacloprid and acetamiprid in environmental water samples with solid-phase extraction packed with multiwalled carbon nanotubes prior to high-performance liquid chromatography[J]. Analytical and Bioanalytical Chemistry, 2006, 385: 1520-1525.
[34] Zhou Q, Xiao J, Wang W. Using multi-walled carbon nanotubes as solid phase extraction adsorbents to determine dichlorodiphenyltrichloroethane and its metabolites at trace level in water samples by high performance liquid chromatography with UV detection[J]. Journal of Chromatography A, 2006, 1125: 152-158.
[35] Zhou Q, Xiao J,Wang W. Trace analysis of triasulfuron and bensulfuron-methyl in water samples using a carbon nanotubes packed cartridge in combination with high-performance liquid chromatography[J]. Microchimica Acta, 2006, 157: 93-98.
[36] Zhou Q, Xiao J, Ding Y. Sensitive determination of fungicides and prometryn in environmental water samples using multiwalled carbon nanotubes solid-phase extraction cartridge[J]. Analytica Chimica Acta, 2007, 602: 223-228.
[37] Zhou Q, Xiao J, Xie G, et al. Enrichment of pyrethroid residues in environmental waters using a multiwalled carbon nanotubes cartridge, and analysis in combination with high performance liquid chromatography[J]. Microchimica Acta, 2008, 164: 419-424.
[38] Ravelo-Pérez L M, Herrera-Herrera A V, Hernández-Borges J, et al. Carbon nanotubes: Solid-phase extraction[J]. Journal of Chromatography A, 2010, 1217: 2618-2641.
[39] Vassileva E, Proinova I, Hadjiivanov K. Solid-phase extraction of heavy metal ions on a high surface area titanium dioxide (anatase)[J]. Analyst, 1996, 121: 607-612.
[40] Liu Y, Liang P,Guo L. Nanometer titanium dioxide immobilized on silica gel as sorbent for preconcentration of metal ions prior to their determination by inductively coupled plasma atomic emission spectrometry[J]. Talanta, 2005, 68: 25-30.
[41] Liu R, Liang P. Determination of gold by nanometer titanium dioxide immobilized on silica gel packed microcolumn and flame atomic absorption spectrometry in geological and water samples[J]. Analytica Chimica Acta, 2007, 604: 114-118.
[42] Liang P, Liu R. Speciation analysis of inorganic arsenic in water samples by immobilized nanometer titanium dioxide separation and graphite furnace atomic absorption spectrometric determination[J]. Analytica Chimica Acta, 2007, 602: 32-36.
[43] Quétel C R, Vassileva E, Petrov I, et al. First results on Fe solid-phase extraction from coastal seawater using anatase TiO2 nano-particles[J]. Analytical and Bioanalytical Chemistry, 2010, 396: 2349-2361.
[44] Zhou Q, Zhao X, Xiao J. Preconcentration of nickel and cadmium by TiO2 nanotubes as solid-phase extraction adsorbents coupled with flame atomic absorption spectrometry[J]. Talanta, 2009, 77: 1774-1777.
[45] Zhou Q, Mao J, Xiao J, et al. Determination of paraquat and diquat preconcentrated with N doped TiO2 nanotubes solid phase extraction cartridge prior to capillary electrophoresis[J]. Analytical Methods, 2010, 2: 1063-1068.
[46] Zhou Q, Ding Y, Xiao J, et al. Investigation of the feasibility of TiO2 nanotubes for the enrichment of DDT and its metabolites at trace levels in environmental water samples[J]. Journal of Chromatography A, 2007, 1147: 10-16.
[47] Niu H, Cai Y, Shi Y, et al. Cetyltrimethylammonium bromide-coated titanate nanotubes for solid-phase extraction of phthalate esters from natural waters prior to high-performance liquid chromatography analysis[J]. Journal of Chromatography A, 2007, 1172: 113-120.
[48] Zhou Q, Huang Y, Xiao J, et al. Micro-solid phase equilibrium extraction with highly ordered TiO2 nanotube arrays: a new approach for the enrichment and measurement of organochlorine pesticides at trace level in environmental water samples[J]. Analytical and Bioanalytical Chemistry, 2011, 400: 205-212.
[49] Huang Y, Zhou Q, Xiao J. Establishment of trace determination method of pyrethroid pesticides with TiO2 nanotube array micro-solid phase equilibrium extraction combined with GC-ECD[J]. The Analyst, 2011, 136: 2741-2746.
[50] Huang Y, Zhou Q, Xie G. Development of micro-solid phase extraction with titanate nanotube array modified by cetyltrimethylammonium bromide for sensitive determination of polycyclic aromatic hydrocarbons from environmental water samples[J]. Journal of Hazardous Materials, 2011, 193: 8.
[51] Sellergren B. Direct drug determination by selective sample enrichment on an imprinted polymer [J]. Analytical Chemistry, 1994, 66: 1578-1582.
[52] Alizadeh T, Ganjali M R, Nourozi P, et al. Multivariate optimization of molecularly imprinted polymer solid-phase extraction applied to parathion determination in different water samples[J]. Analytica Chimica Acta, 2009, 638: 154-161.
[53] Wu G, Wang Z, Wang J, et al. Hierarchically imprinted organic-inorganic hybrid sorbent for selective separation of mercury ion from aqueous solution[J]. Analytica Chimica Acta, 2007, 582: 304-310.