Abstract：After investigating the instrument parameters，matrix effect of zinc，concentration of hexamethylene tetramine in stripping solution，degree of acidity and dosage of HF，a new method for determination of trace antimony in coating of galvanized plate by hydride generation-atomic fluorescence spectrometry has been established. The results indicated that matrix effect of zinc was avoided by matrix matching，40% HCl (V/V) was fit for measurement，dosage of HF less than 2 mL needed for digestion of samples and hexamethylene tetramine in stripping solution almost do not influence the determination of antimony. The fluorescence intensity was linear with the concentration of antimony in the range of 0.001-0.1 μg/mL，with detection limit of 0.2 μg/L. The proposed method has been applied for two galvanized plate samples. The relative standard deviation (RSD) was 1.0% and 1.2%. The recovery rate of antimony was 96%-101%. The results of this method were in a good agreement with those obtained by ICP-MS.
［5］亢德华，于媛君. 电感耦合等离子体质谱法测定再生锌锭中7种痕量元素［C］.中国金属学会第十四届分析测试学术年会论文集（The 14th Annual Conference of Analysis & Test of Chinese Society for Metals），北京，2008，（增1）：400-404.
［6］申治国，黎雪慧，张慧敏. 氢化物-原子荧光法同时测定痕量砷和锑［J］.光谱实验室（Chinese Journal of Spectroscopy Laboratory），2001，18（4）：453-455.
［7］李岩. 氢化物-原子荧光光谱法连续测定锌精矿中砷、锑、铋、锡［J］.分析化学（Chinese Journal of Analytical Chemistry），2004，32（2）：205-208.
