Determination of platinum, palladium, rhodium in metal carrier catalyst for exhaust gas purification by flame atomic absorption spectrometry
SHI Yihua 1,3, WANG Sheng 2, YANG Zhongping 1, JIN Xiaozhu 1,HU Shenghong 3,DENG Shuiping 2
1. Testing Center，Guilin Research Institute of Geology and Mineral Resources，Guilin 541004，China; 2.BASF Catalysts(Guilin) Co., Ltd., Guilin 541004, China; 3. State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan 430074,China
Abstract：A novel method for the determination of platinum, palladium and rhodium in metal carrier catalyst for exhaust gas purification was established by flame atomic absorption spectrometrometry(FAAS). The sample decomposition method, coprecipitation condition, interference factor and elimination method were studied. The metal carrier catalyst sample for exhaust gas purification was treated by hydrochloric acidultrasonic wave, and filtrated. The insoluble substance was decomposed with sodium peroxide and acidized with hydrochloric acid, and then it was mixed with sample solution. 10 mg of tellurium oxide and 10 mL of 200 g/L SnCl2 solution were added to sample solution in the medium of 23 mol/L hydrochloric acid for the coprecipitation, enrichment and separation of palladium, platinum and rhodium from matrix elements such as Fe, Ni, Al, Cr and Na. After the coprecipitate was dissolved with aqua regia, the content of palladium, platinum and rhodium was determined by flame atomic absorption spectrometry. The detection limits of method for Pt, Pd and Rh are 4.72,1.13 and 1.06,respectively. The proposed method was applied to the determination of actual samples, and the results were consistent with those obtained by inductively coupled plasma atomic emission spectrometry. The relative standard deviations (RSD, n=11) for palladium, platinum and rhodium were 3.0%, 1.9% and 4.2%, respectively.
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