Abstract:Iron ore occupied an important position in national industrial production. The quality and harmful elements content varied for the iron ores from different origins. In order to improve the recognition and early warning ability of customs in potential risks of imported iron ores such as concealing the origin and selling as shoddy, the artificial intelligence was used to solve these problems. Total 1 072 batches of imported iron ore samples from Australia, Pakistan, Brazil, South Africa, Ukraine and India were selected as the research objects. Fifteen indexes including Hg, F, Cl, S, total iron (TFe), SiO2, Al2O3, P, H2O, L.O.I, K2O, TiO2, MgO, CaO and Mn were detected according to the national standard and industrial standard methods. Five effective principal components were extracted by principal component analysis. The cumulative variance contribution rate was 77.481%. Five main factors extracted in principal component analysis were used as the input indexes of neural network, and six different origins were used as the output indexes. 80% of the testing data in 1 072 groups were randomly selected as the training set to establish the analysis model. The rest data were used as validation set to verify the prediction accuracy of model. It was found that the recognition accuracy rate was 100%, which realized the accurate origin recognition of iron ores from six nations. The establishment of this model could be directly used for the origin identification of imported iron ores to regulate the risk of imported iron ores and secure the trade order and facilitation.
王虹, 魏秉炎, 王昊云. 基于主成分分析的BP神经网络模型在铁矿产地溯源中的应用[J]. 冶金分析, 2021, 41(9): 11-17.
WANG Hong, WEI Bingyan, WANG Haoyun. Application of BP neural network model based on principal component analysis in tracing the origin of iron ore. , 2021, 41(9): 11-17.
[1] 生态环境部.2021年将不再受理和审批固体废物进口相关申请[J].资源再生(Resource Recycling),2020(6):2. [2] 王静静,房芳,周晓明,等.基于矿物元素含量的葡萄干产地溯源[J].新疆农业科学(Xinjiang Agricultural Sciences),2020,57(1):69-77. [3] 王宁丽,于培良,赵立春,等.不同产地海地瓜活性物质检测及降糖活性评价[J].中国海洋药物,2019,38(2):11-16. WANG Ningli,YU Peiliang,ZHAO Lichun,et al.Determination of active substances and evaluation of hypoglycemic activity in acaudinamolpadioides from different producing areas[J].Chinese Journal of Marine Drugs,2019,38(2):11-16. [4] 贺媛媛,孙倩倩,郭波莉,等.矿质元素指纹分析在野葛产地溯源中的应用[C]//中国食品科学技术学会第十六届年会暨第十届中美食品业高层论坛.武汉:中国食品科学技术学会,2019. [5] 杨健,周利,胡玲,等.ICP-MS法分析不同产地何首乌中40种无机元素[J].世界中医药,2019,14(11):2819-2828. YANG Jian,ZHOU Li,HU Ling,et al.Quantitative analysis of 40 inorganic elements in Polygoni Multiflori Radix from different origins by ICP-MS[J].World Chinese Medicine,2019,14(11):2819-2828. [6] 任春生,付冉冉,王艳,等.SPSS软件对铁矿中微量元素含量的统计分析[J].化学分析计量,2014,23(2):80-84,93. REN Chunsheng,FU Ranran,WANG Yan,et al.Statistical analysis of trace elements in iron ores by SPSS Software[J].Chemical Analysis and Meterage,2014,23(2):80-84,93. [7] 陈健,刘文中,陈萍.SPSS在淮南矿区煤中微量元素研究中的应用[J].选煤技术(Goal Preparation Technology),2009(2):46-50,81. [8] 魏红兵,刘青山,孙世明,等.矿物组分“数字指纹”模型的建立和应用[J].工业技术经济,2010(11):107-111. WEI Hongbing,LIU Qingshan,SUN Shiming,et al.Establishment and application of mineral constituents "digital fingerprint" model[J].Industrial Technology & Economy,2010(11):107-111. [9] 武素茹,谷松海,宋义,等.进口铁矿产地鉴别模型的建立[J].计算机与应用化学,2014,31(12):1543-1546. WU Suru,GU Songhai,SONG Yi,et al.Establishment of origin identification model of import iron ores[J].Computers and Applied Chemistry,2014,31(12):1543-1546. [10] 张博,闵红,刘曙,等.X射线荧光光谱结合判别分析识别进口铁矿石产地及品牌[J].光谱学与光谱分析,2020,40(8):2640-2646. ZHANG Bo,MIN Hong,LIU Shu,et al.X-ray fluorescence spectroscopy combined with discriminant analysis to identify imported iron ore origin and brand[J].Spectroscopy and Spectral Analysis,2020(8):2640-2646. [11] 张开春,吴丽萍,姚军,等.X荧光谱与人工神经网络相结合对陶片产地识别的研究[J].核技术,2006(11):56-60. ZHANG Kaichun,WU Liping,YAO Jun,et al.Study of recognition of production areas for ceramic fragments by X-fluorescence spectrum combined with artificial neural network[J].Nuclear Techniques,2006(11):56-60. [12] 陈永明,林萍,何勇.基于遗传算法的近红外光谱橄榄油产地鉴别方法研究[J].光谱学与光谱分析,2009,29(3):671-674. CHEN Yongming,LIN Ping,HE Yong.Study on discrimination of producing area of olive oil using near infrared spectra based on genetic algorithms[J].Spectroscopy and Spectral Analysis,2009,29(3):671-674. [13] Giulio Binetti,Coco L D,Ragone R,et al.Cultivar classification of apulian olive oils: use of artificial neural networks for comparing NMR, NIR and merceological data[J].Food Chemistry,2017,219:131-138. [14] Khajehzadeh N,Haavisto O,Koresaar L.On-stream mineral identification of tailing slurries of an iron ore concentrator using data fusion of LIBS, reflectance spectroscopy and XRF measurement techniques[J].Minerals Engineering,2017,113:83-94. [15] 张立明.人工神经网络的模型及其应用[M].上海:复旦大学出版社,1993:46. [16] 吕砚山,赵正琦.BP神经网络的优化及应用研究[J].北京化工大学学报(自然科学版),2001(1):67-69. LÜ Yanshan,ZHAO Zhengqi.Optimization and application research of BP neural network[J].Journal of Beijing University of Chemical Technology(Natural Science Edition),2001(1):67-69.