Classification and identification of scrap metals based on laser-induced breakdown spectroscopy
GUO Mei-ting1,2,3, SUN Lan-xiang*1,2,3, DONG Wei1,2,3, WANG Jin-chi1,2,3, CONG Zhi-bo1,2,3, ZHENG Li-ming1,2,3
1. State Key Laboratory of Robotics, Shenyang Institute of Automation, Chinese Academy of Sciences, Shenyang110016, China; 2. Key Laboratory of Networked Control Systems, Chinese Academy of Sciences, Shenyang 110016,China; 3. Institutes for Robotics and Intelligent Manufacturing, Chinese Academy of Sciences, Shenyang 110169, China
Abstract:Scrap metal recycling was one of the important sources of metals in industry and an important part of developing recycling economy. The production of scrap metal was huge. Usually the surface was covered with impurity and the shape was irregularity. The classification method with strong discriminant ability and fast calculation speed was required. Seven kinds of classification and identification problems for scrap metal, including cast aluminum, wrought aluminum, magnesium, stainless steel, zinc, brass and red copper, were studied and analyzed by means of laser-induced breakdown spectroscopy (LIBS). In order to meet the field application conditions, samples were classified based on optical emission following a single laser pulse in the experiment. Support vector machine (SVM) model, support vector machine combined with principal component analysis (PCA-SVM) model, support vector machine combined with genetic algorithm (GA-SVM) model, support vector machine combined with genetic algorithm and principal component analysis (GA-PCA-SVM) model and back-propagation neural network combined with genetic algorithm and principal component analysis (GA-PCA-BP) model were established and compared. The characteristic spectral segments with ample feature information and less interference were extracted by genetic algorithm. A novel method combining genetic algorithm and support vector machine was proposed, resulting the percentage of 490 validation samples correctly identified was 93.47%. In order to assess the robustness and versatility of the model, a group of new samples were tested on a self-developed sorting system with a conveyor belt running at a uniform speed. The 750 test samples could be classified with 88.27% correct assignments, which proved that the GA-SVM model had good portability and applicability.
Rajamani Raj,Nagel James,Dholu Nakul.Electrodynamic sorting of light metals and alloys[C]//[S.l.]:John Wiley & Sons,Ltd.,2016.
[2]
李尊德.再生资源利用必须走自动智能分拣之路[J].资源再生,2010(5):69-70.LI Zun-de.The utilization of renewable resources must take the road of automatic and intelligent sorting[J].Resource Recycling,2010(5):69-70.
[3]
周春芳,周占兴.新型的废金属破碎分选生产线发展设想[J].冶金设备,2014(212):130-132.ZHOU Chun-fang,ZHOU Zhan-xing.Development assumption of a new production line of scrap metal crushing and sorting[J].Metallurgical Equipment,2014(212):130-132.
[4]
王茜蒨,黄志文,刘凯,等.基于主成分分析和人工神经网络的激光诱导击穿光谱塑料分类识别方法研究[J].光谱学与光谱分析,2012,32(12):3179-3182.WANG Qian-qian,HUANG Zhi-wen,LIU Kai,et al.Classification of plastics with laser-induced breakdown spectroscopy based on principal component analysis and artificial neural network model[J].Spectroscopy and Spectral Analysis,2012,32(12):3179-3182.
[5]
于洋,郝中骐,李常茂,等.支持向量机算法在激光诱导击穿光谱技术塑料识别中的应用研究[J]. 物理学报,2013,62(21):290-296.YU Yang,HAO Zhong-qi,LI Chang-mao,et al.Identification of plastics by laser-induced breakdown spectroscopy combined with support vector machine algorithm[J].Acta Physica Sinica,2013,62(21):290-296.
[6]
余琦,马晓红,王锐,等.基于LIBS技术和主成分分析的快速分类方法研究[J].光谱学与光谱分析,2014,34(11):3095-3099.YU Qi,MA Xiao-hong,WANG Rui,et al.Research on fast classification based on LIBS technology and principle component analyses[J].Spectroscopy and Spectral Analysis,2014,34(11):3095-3099.
[7]
Gurell J,Bengtson A,Falkenstrom M,et al.Laser induced breakdown spectroscopy for fast elemental analysis and sorting of metallic scrap pieces using certified reference materials[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2012,74-75:46-50.
[8]
Merk S,Scholz C,Florek S,et al.Increased identification rate of scrap metal using laser induced breakdown spectroscopy echelle spectra[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2015,112:10-15.
[9]
Campanella B,Grifoni E,Legnaioli S,et al.Classification of wrought aluminum alloys by Artificial Neural Networks evaluation of laser induced breakdown spectroscopy spectra from aluminum scrap samples[J].Spectrochimica Acta,2017,134:52-57.
Zhang P,Sun L X,Kong H Y,et al.A method derived from genetic algorithm, principal component analysis and artificial neural networks to enhance classification capability of laser-induced breakdown spectroscopy[C]//Optical Spectroscopy and Imaging.Beijing:[s.n.],2017:1046107.