Discussion on identification of solid waste property of one imported “iron ore sinter”
LÜ Xiaohua1, ZHANG Xulong 2, ZHANG Jinlong*1, ZHANG Qingjian3 HU Xiaoxia1, WANG Ting1
1. Urumqi Customs Technology Center,Urumqi 830063,China; 2. Science and Technology Research Center of China Customs,Beijing 100026,China; 3. School of Environment and Municipal Engineering, Qingdao University of Technology,Qingdao 266520,China
Abstract:A general method for identifying the properties of solid waste minerals was established for a specific imported “iron ore sinter”.X-ray fluorescence spectrometry (XRF),X-ray diffraction (XRD),mineral liberation analyzer(MLA) and scanning electron microscopy-X-ray energy dispersive analysis (SEM-EDS) were used to analyze the appearance,microscopic morphology,phase composition and chemical composition of the target sample.The discussion was focused on whether this sample belonged to solid waste or not.The results showed that the main phases of the sample were magnetite,hematite,pyroxene and bassanite.Moreover,it also contained a small amount of chalcopyrite,matte,covellite,sphalerite,franklinite and quartz,as well as a small amount of glassy potassium-sodium-aluminum silicate minerals(leucosphenite), calcium-iron-aluminum-silicates(melilite),fayalite and zincate/ferrate.Some silicates showed loose gel-like structure,while some hematite ores exhibited solid-melt texture.The sample contained the substances produced in pyrometallurgical process.The components and microstructure of the sample were significantly different from the iron ore sinter obtained from the sintering processes of natural iron ore.The sample had the characteristics of mixture containing the products from pyrometallurgical process.Through the comprehensive analysis,this sample should be from the by-products in the manufacturing process of iron-containing materials,and its characteristics did not meet quality standards required for iron sinter.Therefore, based on GB 34330-2017 General Rules for Identification Standards for Solid Waste Properties, the sample could be identified as the solid waste.
[1] 余淑媛,李勇,刘冬,等.一例进口“铁矿”的属性鉴别研究[J].化工管理,2019(12):113-117. YU Shuyuan,LI Yong,LIU Dong,et al.Research on identification of an imported “iron ore”[J].Chemical Management,2019(12):113-117. [2] 郝雅琼.关于进口含铁物料的固体废物鉴别方法研究[J].环境与可持续发展,2016,41(4):150-152. HAO Yaqiong.Study on solid waste identification methods for imported iron containing materials[J].Environ-ment and Sustaninable Development,2016,41(4):150-152. [3] 冯均利,吴景武,余淑媛,等.进口含铁物料固体废物属性鉴别的探讨[J].冶金分析,2018,38(2):18-24. FENG Junli,WU Jingwu,YU Shuyuan,et al.Discussion on identification of solid waste in imported iron containing material[J].Metallurgical Analysis,2018,38(2):18-24. [4] 赵彤,彭杰,冯均利,等.进口铝物料固体废物鉴别方法探讨[J].冶金分析,2022,42(1):31-35. ZHAO Tong,PENG Jie,FENG Junli,et al.Study on identification method of imported aluminum solid waste[J].Metallurgical Analysis,2022,42(1):31-35. [5] 查燕青,戴东情,卜松涛,等.几种不同含钴物料的表征及属性鉴别[J].冶金分析,2022,42(8):42-47. ZHA Yanqing,DAI Dongqing,BU Songtao,et al.Characterization and attribute identification of several different cobalt-containing materials[J].Metallurgical Analysis,2022,42(8):42-47. [6] 王鹏,夏冬前.关于正确区分固体废物与副产品/副产物工作的探讨[J].山东化工,2022,51(15):208-209. WANG Peng,XIA Dongqian.Discussion on correctly distinguishing solid waste and by-products/by-products[J].Shandong Chemical Industry,2022,51(15):208-209. [7] 郝雅琼.无机物料固体废物属性鉴别通用方法[J].冶金分析,2019,39(10):23-29. HAO Yaqiong.A general method for solid waste identification of inorganic materials[J].Metallurgical Analysis,2019,39(10):23-29. [8] 温大威.宝钢烧结矿质量状况分析[J].宝钢技术,1988(4):10-14. WEN Dawei.Analysis of sinter quality in Bao steel[J].Baosteel Technology,1988(4):10-14. [9] 向小平,刘武杨,李东升.柳钢烧结矿的化学成分及显微结构分析[J].烧结球团,2020,45(2):21-25,30. XIANG Xiaoping,LIU Wuyang,LI Dongsheng.Analysis of chemical composition and microstructure of Liugang sinter[J].Sintering and Pelletizing,2020,45(2):21-25,30. [10] 中华人民共和国工业和信息化部. YB/T 421—2014铁烧结矿[S].北京:冶金工业出版社,2014. [11] 王航民.利用光学显微镜进行烧结矿矿相的分析[J].理化检验(物理分册),2015,51(5):332-336. WANG Hangmin.Analysis on sinter mineralogical using metallographic microscope[J].Physical Testing and Chemical Analysis(Part A:Physical Testing),2015,51(5):332-336. [12] 赵伟,封亚辉,戴东情.冶炼钢铁过程中多种固体废物的鉴别[J].冶金分析,2015,35(10):49-53. ZHAO Wei,FENG Yahui,DAI Dongqing.Identification of various solid wastes in the iron and steel smelting process[J].Metallurgical Analysis,2015,35(10):49-53. [13] 包燕,冯捷.钢铁冶金学教程[M].北京:冶金工业出版社,2008:2-57. [14] 萧达辉,梁悦锋,蒋中鸣,等.焙烧硫铁矿的鉴别及其固体废物属性探讨[J].中国口岸科学技术,2022,4(9):20-25. XIAO Dahui,LIANG Yuefeng,JIANG Zhongming,et al.Identification of roasted pyrite and discussion on its solid waste attribute[J].China Port Science and Technology,2022,4(9):20-25. [15] 武素茹,郑云龙,王斌.硫铁矿渣的固体废物属性特征表征[J].冶金分析,2021,41(10):36-41. WU Suru,ZHENG Yunlong,WANG Bin,et al.Comprehensive characterization of solid waste identification of sintered slag of pyrite[J].Metallurgical Analysis,2021,41(10):36-41. [16] 纪罗军.硫铁矿烧渣资源的综合利用[J].硫酸工业,2009(1):1-8. JI Luojun.Comprehensive utilization of pyrite cinder resource[J].Sulphuric Acid Industry,2009(1):1-8. [17] 张琪,张云春,龚凡涵,等.固体废物铜熔炼渣的快速鉴定[J].冶金分析,2014,34(3):39-42. ZHANG Qi,ZHANG Yunchun,GONG Fanhan,et al.Rapid identification of copper smelter slag for solid waste[J].Metallurgical Analysis,2014,34(3):39-42. [18] 唐梦奇,阮贵武,刘国文,等.湿法炼锌浸出渣和黄钾铁矾渣的鉴别[J].冶金分析,2016,36(12):13-17. TANG Mengqi,RUAN Guiwu,LIU Guowen,et al.Identification of leaching residue of zinc hydrometallurgy and jarosite residue[J].Metallurgical Analysis,2016,36(12):13-17. [19] 刘之能,任佳,方昊,等.从硫酸烧渣中获取高品位铁精矿的技术[J].矿冶,2015,24(6):83-86. LIU Zhineng,REN Jia,FANG Hao,et al.Technology of obtaining high-grand ion concent rate from pyrite cinder[J].Mining & Metallurgy,2015,24(6):83-86. [20] 叶志平,何国伟.硫酸渣资源化及其以废治废技术研究[J].华南师范大学学报(自然科学版),2010(2):72-75. YE Zhiping,HE Guowei.Research on recycling technology and waste water treatment with sulfuric acid residue [J].Journal of South China Normal University(Natutal Science Edition),2010(2):72-75.