金属材料中氢元素检测评述

doi:10.13228/j.boyuan.issn1000-7571.012511

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摘要对金属材料开发利用水平的提升,需要精准把控金属材料的物理特性和机械性能,氢元素对这类性能的影响尤为关键。本文简述氢元素对金属材料性能的影响和危害,并介绍了近些年金属材料中氢元素含量测定方法,主要包括物理化学方法、管式炉加热-热导/红外法、惰气保护脉冲炉加热-热导/红外法、惰气保护脉冲炉加热-质谱法、热解吸-质谱法等,并分别概述了相应分析原理、仪器结构及技术特点。对这些方法所适用的检测对象、分析范围、检测限等指标进行总结,使得相关领域的分析检测人员能够对金属材料中氢含量检测有一个比较全面的了解。

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	周伟
	杨敬巍
	王学华
	孙烨
	王闰鹏
	何源

关键词 ：金属材料, 氢, 检测, 方法, 仪器

Abstract：To enhance the development and utilization of metal materials, the precise control of physical properties and mechanical performance of metal materials is crucial, wherein the hydrogen plays a particularly key role in influencing these aspects. In this paper, the impact and hazards of hydrogen on the performance of metal materials were summarized. The methods for determining hydrogen content in metal materials in recent years were introduced, mainly including physicochemical method, tube furnace heating-thermal conductivity/infrared method, inert gas protection pulse furnace heating-thermal conductivity/infrared method, inert gas protection pulse furnace heating-mass spectrometry method, thermal desorption-mass spectrometry method, etc. The corresponding analysis principles, instrument structures, and technical characteristics were summarized. The review of applicable detection objects, analysis range, detection limits, and other specifications could enable the technicians in relevant fields to have a comprehensive understanding of hydrogen content detection in metal materials.

Key words： metal material hydrogen detection method instrument

收稿日期: 2024-03-11

ZTFLH:	O659.2
	TF03+1

基金资助:2023年国家新材料重点平台-新材料测试评价平台(苏州区域中心);江苏省院士工作站;钢研纳克江苏检测技术研究院建设

通讯作者: 王学华(1978-),男,高级工程师,硕士,研究方向为金属材料中气体元素分析方法和设备开发与应用;E-mail:wangxuehua@ncschina.com

作者简介: 周伟(1978-),男,高级工程师,硕士,研究方向为仪器分析设备与方法开发、气体元素分析等;E-mail:zhouwei@ncschina.com

引用本文:

周伟, 杨敬巍, 王学华, 孙烨, 王闰鹏, 何源. 金属材料中氢元素检测评述[J]. 冶金分析, 2024, 44(8): 27-33. ZHOU Wei, YANG Jingwei, WANG Xuehua, SUN Ye, WANG Runpeng, HE Yuan. A review of hydrogen detection in metal materials. , 2024, 44(8): 27-33.

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http://yjfx.chinamet.cn/CN/10.13228/j.boyuan.issn1000-7571.012511 或 http://yjfx.chinamet.cn/CN/Y2024/V44/I8/27

[1] 王蓬,王海舟.金属中氢的分析技术进展[J].冶金分析,2007,27(3):37-44.
WANG Peng,WANG Haizhou.Recent progress in analytical technologies of hydrogen in metal[J].Metallurgical Analysis,2007,27(3):37-44.
[2] Shen,Sicong,Song,et al.Effect of tempering temperature and inclusions on hydrogen-assisted fracture behaviors of a low alloy steel[J].Materials Science & Engineering,A.Structural Materials:Properties, Misrostructure and Processing,2017,682:359-369.
[3] 徐继红,徐必靖,宋明刚.钢中氢含量的研究与实践[J].福建冶金,2023,52(6):15-16,24.
XU Jihong,XU Bijing,SONG Minggang.Research and practice of hydrogen content in steel[J].Fujian Metallurgy,2023,52(6):15-16,24.
[4] Jeffrey,Venezuela,Qing long,et al.A review of hydrogen embrittlement of martensitic advanced high-strength steels[J].Corrosion Reviews,2016,34(3):153-186.
[5] 曹志海,蓝凤林.真空热抽取气相色谱法快速测定氢[J].分析化学(Chinese Journal of Analytical Chemistry),1975(4):295-298.
[6] 杨珉.用氩载气熔融色谱法快速测定金属中的氢[J].钢铁研究情报(Research on Iron and Steel),1974(2):54-59.
[7] 欧阳跃军.氢在钢中的扩散与氢渗透传感器的研究[D].长沙:湖南大学,2013.
[8] Ogawa Y,Takakuwa O,Okazaki S,et al.Pronounced transition of crack initiation and propagation modes in the hydrogen-related failure of a Ni-based superalloy 718 under internal and external hydrogen conditions[J].Corrosion science,2019,161:108-186.
[9] Michler,Thorsten & Naumann,Jörg.Coatings to reduce hydrogen environment embrittlement of 304 austenitic stainless steel[J].Surface and Coatings Technology,2009,203:1819-1828.
[10] 李星国.金属的氢脆及其产生机制[J].上海金属,2023,45(5):1-16.
LI Xingguo.Hydrogen embrittlement of metals and its mechanism[J].Shanghai Metals,2023,45(5):1-16.
[11] 宋北,马青军,杨子佳,等.熔敷金属中扩散氢测试方法的研究进展[J].机械制造文摘(焊接分册),2016(1):41-43.
SONG Bei,MA Qingjun,YANG Zijia,et al.The research of diffused testing method in deposited metal[J].Welding Digest of Machinery Manufacturing,2016(1):41-43.
[12] 杨维琛,李捷报,张素荣,等.无汞真空套管色谱法测定固态铝及铝合金中的氢[J].轻金属(Light Metals),1984(11):40-45.
[13] 胡少成,沈学静,王蓬.固态金属及合金材料中氧、氮、氢联测技术进展[J].冶金分析,2009,29(11):34-40.
HU Shaocheng,SHEN Xuejing,WANG Peng.Development of simultaneous analysis technique for oxygen,nitrogen and hydrogen in solid metals and alloys[J].Metallurgical Analysis,2009,29(11):34-40.
[14] 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T 3965—2012熔敷金属中扩散氢测定方法[S].北京:中国标准出版社,2012.
[15] 陶映初,姚禄安,吕德义,等.用脉冲-色谱法测定腐蚀后钢中含氢量[J].武汉大学学报(自然科学版),1984(4):75-80.
TAO Yingchu,YAO Lu'an,LÜ Deyi,et al.the Determination of hydrogen content in corroded steel by NCFGC method[J].Journal of Wuhan University (Natural Science Edition),1984(4):75-80.
[16] 宋忠训.脉冲色谱法测定金属铬中的氢[J].分析试验室,1996(2):83-85.
SONG Zhongxun.The determination of hydrogen contents in chromium by impulse heating gas chromatography[J].Chinese Journal of Analysis Laboratory,1996(2):83-85.
[17] 刘攀,张毅,张健豪,等.脉冲加热-惰气熔融-热导法测定B30铜镍合金中氢[J].冶金分析,2022,42(11):37-43.
LIU Pan,ZHANG Yi,ZHANG Jianhao,et al.Determination of hydrogen in B30 cupronickel alloy by pulse heating-inert gas fusion-thermal conductivity method [J].Metallurgical Analysis,2022,42(11):37-43.
[18] 朱跃进,孙明月,李素娟,等.定氢钢样制备方法研究[J].冶金分析,2013,33(7):16-20.
ZHU Yuejin,SUN Mingyue,LI Sujuan,et al.Research on the preparation method of steel sample for hydrogen analysis[J].Metallurgical Analysis,2013,33(7):16-20.
[19] 赵飞,杨军红,王芳.热导法测定锆合金中氢含量的不确定度评定[J].安徽化工,2017,43(1):85-86.
ZHAO Fei,YANG Junhong,WANG Fang.Evaluation of uncertainty in the measurement of hydrogen content in zirconium alloy by thermal conductivity method[J].Anhui Chemical Industry,2017,43(1):85-86.
[20] 侯红霞,杨倩倩,李美玲.脉冲加热惰气熔融-热导法测定钕铁硼合金中氢的分析方法探索[C]// CCATM'2014国际冶金及材料分析测试学术报告会会议摘要.北京:中国金属学会,2014.
[21] 朱跃进,朱瑛才.金属中气体元素分析典型案例[J].冶金分析,2022,42(1):1-9.
ZHU Yuejin,ZHU Yingcai.Typical case study on analysis of gaseous element in metal[J].Metallurgical Analysis,2022,42(1):1-9.
[22] 马琪,朱秀慧,王博,等.惰气脉冲熔融红外吸收法测定钨合金中氢[J].冶金分析,2020,40(9):53-56.
MA Qi,ZHU Xiuhui,WANG Bo,et al. Determination of hydrogen in tungsten alloy by inert gas pulse fusion infrared absorption method[J].Metallurgical Analysis,2020,40(9):53-56.
[23] 赵亚恒,郭慧娟,宋西平.锆合金中氢含量称重法、化验法及金相法表征的相关性[J].理化检验(物理分册),2023,59(10):8-12.
ZHAO Yaheng,GUO Huijuan,SONG Xiping.Correlation of characterization of hydrogen content in zirconium alloy by weighing method,chemical method and metallographic methods[J].Physical Testing and Chemical Analysis(Part A:Physical Testing),2023,59(10):8-12.
[24] 王宽,高东旭,王芳,等.惰气熔融-红外吸收法测定钽钨合金中氢[J].冶金分析,2022,42(4):34-37.
WANG Kuan,GAO Dongxu,WANG Fang,et al.Determination of hydrogen in tantalum-tungsten alloy by inert gas fusion-infrared absorption method[J].Metallurgical Analysis,2022,42(4):34-37.
[25] 杨峥,李蓓,梁钪,等.脉冲加热惰气熔融-红外吸收法测定高纯金属铬中氢[J].冶金分析,2023,43(8):74-78.
YANG Zheng,LI Bei,LIANG Kang,et al.Determination of hydrogen in high purity metal chromium by pulse heating inert gas fusion-infrared absorption method[J].Metallurgical Analysis,2023,43(8):74-78.
[26] 钟华.脉冲加热-红外吸收光谱法测定钒铝合金中氢[J].中国无机分析化学,2013,3(2):56-59.
ZHONG Hua.Determination of hydrogen in vanadium-aluminum alloy by pulsed heating and infrared absorption method[J].Chinese Journal of Inorganic Analytical Chemistry,2013,3(2):56-59.
[27] 沈学静,王蓬,胡少成,等.脉冲熔融-飞行时间质谱法测定金属材料中氧、氮、氢和氩[J].分析化学,2011,39(10):1555-1560.
SHEN Xuejing,WANG Peng,HU Shaocheng,et al. Simultaneous determination of oxygen, nitrogen, hydrogen and argon in metals by pulsed heating and time of flight mass spectrometry[J].Chinese Journal of Analytical Chemistry,2011,39(10):1555-1560.
[28] 杨倩倩,马红权,郭飞飞,等.脉冲熔融-飞行时间质谱法测定Nd-Fe-B材料中的氧、氮、氢[J].中国无机分析化学,2013,3(4):38-40.
YANG Qianqian,MA Hongquan,GUO Feifei,et al.Simultaneous determination of oxygen,nitrogen and hydrogen in Nd-Fe-B by pulsed melting-time of flight mass spectrometry[J].Chinese Journal of Inorganic Analytical Chemistry,2013,3(4):38-40.
[29] Tapia-Bastidas C V,Atrens A,Gray E M.Thermal desorption spectrometer for measuring ppm concentrations of trapped hydrogen[J].International Journal of Hydrogen Energy,2018,43:7600-7617.
[30] Pérez E D,Verbeken K,Duprez L,et al.Evaluation of hydrogen trapping in high strength steels by thermal desorption spectroscopy[J].Materials Science & Engineering:A,2012,551(31):50-58.
[31] Kei,Saito,Tetsuya,et al.Hydrogen desorption spectra from excess vacancy-type defects enhanced by hydrogen in tempered martensitic steel showing quasi-cleavage fracture[J].Metallurgical and Materials Transactions A,2019,50(11):5091-5102.
[32] 程笑,钱维锋,李秀磊,等.金属的氢脆机理及测试方法[J].轻合金加工技术,2023,51(8):46-52,63.
CHENG Xiao,QIAN Weifeng,LI Xiulei,et al.Hydrogen embrittlement mechanism and testing methods of metals[J].Light Alloy Fabrication Technology,2023,51(8):46-52,63.
[33] 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T 3965—2012 熔敷金属中扩散氢测定方法[S].北京:中国标准出版社,2013.
[34] 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T4698.15—2011 海绵钛、钛及钛合金化学分析方法氢量的测定[S].北京:中国标准出版社,2011.
[35] 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会. GB/T 223.82—2018 钢铁氢含量的测定惰气脉冲熔融热导法或红外法[S].北京:中国标准出版社,2018.
[36] 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T 223.82—2007 钢铁氢含量的测定惰气脉冲熔融热导法[S].北京:中国标准出版社,2008.
[37] 美国材料与试验协会.ASTM E2792-2013 Standard test method for determination of hydrogen in aluminum and aluminum alloys by inert gas fusion[S].Pennsylvania:J&J Editorial,2013.
[38] 中华人民共和国工业和信息化部,全国钢标准化技术委员会.YB/T 4307—2012 钢铁及合金氧、氮和氢含量的测定脉冲加热惰气熔融-飞行时间质谱法(常规法)[S].北京:中国标准出版社,2012.