Abstract：This paper reported the method for the determination of Si, P, Cu, S, Mn, As, Ti, Sn, V, Cr, Ni, Mo and Al in cast iron by X-ray fluorescence (XRF) spectrometry with power pressed method. The sample was pretreated with low-temperature annealing method, and during the sample-molding process, ten drops of mixed solution with certain ratio of rosin and acetone in the adhesive layer. The method selected fifteen national/ministerial grade and self-made standard samples to prepare a standard series of sample for establishing the calibration curve. The blank sample coefficient correction method was employed for calibrating the interference resulted from the overlaps of spectrum lines. Theoretical alpha coefficient and empirical coefficient was combined to overcome the sample spectral interference and matrix effect. The results of the proposed method were consistent with those of inductively coupled plasma spectrometry and spark source optical emission spectrometry.
武映梅，石仕平，宋武元 . X射线荧光光谱粉末压片法检测合金铸铁中13种成分[J]. 冶金分析, 2012, 32(7): 32-37.
WU Ying-mei, SHI Shi-ping, SONG Wu-yuan. Determination of thirteen components in cast iron by X-ray fluorescence spectrometry with power press method.. , 2012, 32(7): 32-37.
